Hydroxylamine-O-Sulfonic Acid

Hydroxylamine-O-Sulfonic Acid Structure
Hydroxylamine-O-Sulfonic Acid structure
Common Name Hydroxylamine-O-Sulfonic Acid
CAS Number 2950-43-8 Molecular Weight 113.093
Density 2.0±0.1 g/cm3 Boiling Point N/A
Molecular Formula H3NO4S Melting Point 210 °C (dec.)(lit.)
MSDS Chinese USA Flash Point N/A
Symbol GHS05
GHS05
Signal Word Danger

Elusive metal-free primary amination of arylboronic acids: synthetic studies and mechanism by density functional theory.

J. Am. Chem. Soc. 134(44) , 18253-6, (2012)

Herein, we disclose the first metal-free synthesis of primary aromatic amines from arylboronic acids, a reaction that has eluded synthetic chemists for decades. This remarkable transformation affords structurally diverse primary arylamines in good chemical yi...

Co-immobilization of semaphorin3A and nerve growth factor to guide and pattern axons.

Acta Biomater. 28 , 33-44, (2015)

Immobilization of axon guidance cues offers a powerful tissue regenerative strategy to control the presentation and spatial location of these biomolecules. We use our previously developed immobilization strategy to specifically tether recombinant biotinylated...

Aminations of guanosine and deoxyguanosine with hydroxylamine-O-sulfonic acid and 2,4-dinitrophenoxyamine. Dependence on the reaction medium.

Nucleic Acids Symp. Ser. (17) , 145-8, (1986)

Amination of guanosine (Guo) with 2,4-dinitrophenoxyamine in aqueous DMF gave 7-amino-Guo, which was readily converted to 8,5'-O-cyclo-Guo, and 8-hydroxy-Guo. Deoxyguanosine (dG) gave only deglycosylated 7-amino-G under the same reaction condition. Aminations...

Mechanism of metal-mediated DNA damage induced by metabolites of carcinogenic 2-nitropropane.

Mutat. Res. 479(1-2) , 101-11, (2001)

2-Nitropropane (2-NP), a widely used industrial solvent, is carcinogenic to rats. To clarify the mechanism of carcinogenesis by 2-NP, we investigated DNA damage by 2-NP metabolites, N-isopropylhydroxylamine (IPHA) and hydroxylamine-O-sulfonic acid (HAS), usin...

The reaction of organoboranes with chloramine and with hydroxylamine-O-sulfonic acid. A convenient synthesis of amines from olefins via hydroboration. Brown HC, et al.

J. Am. Chem. Soc. 86(17) , 3565-3566, (1964)

Hydroxylamine-O-sulfonic Acid. Erdik E and Saczewski J.

e-EROS Encyclopedia of Reagents for Organic Synthesis. , (2013)

Synthesis and molecular structure of (Z)-1H-purin-6-ylideneaminooxysulfonic acid: a possible secondary metabolite of adenine. Saczewski J and Gdaniec M.

Heterocycl. Comm. 18(3) , 109-112, (2012)

Amination of tetrazoles with hydroxylamine-O-sulfonic acid: 1-and 2-aminotetrazoles. Raap R.

Can. J. Chem. 47(19) , 3677-3681, (1969)

N-Trinitroethylamino functionalization of nitroimidazoles: a new strategy for high performance energetic materials. Yin P, et al.

J. Mater. Chem. A 1(25) , 7500-7510, (2013)

A New Strategy for the Preparation of N-Aminopiperidine Using Hydroxylamine-O-Sulfonic Acid: Synthesis, Kinetic Modelling, Phase Equilibria, Extraction and Processes. Labarthe E, et al.

Adv. Chem. Eng. Sci. 3(2) , (2013)