dihydronaphthalene
dihydronaphthalene structure
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Common Name | dihydronaphthalene | ||
|---|---|---|---|---|
| CAS Number | 447-53-0 | Molecular Weight | 130.186 | |
| Density | 1.0±0.1 g/cm3 | Boiling Point | 204.9±15.0 °C at 760 mmHg | |
| Molecular Formula | C10H10 | Melting Point | −8 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 67.2±0.0 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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'Bridged' stilbene derivatives as selective cyclooxygenase-1 inhibitors.
Bioorg. Med. Chem. 15 , 6109-18, (2007) Resveratrol ((E)-3,4',5-trihydroxy-stilbene), a phytoalexin found in various plants, shows non-selective cyclooxygenase-1 (COX-1) and cyclooxygenase-2 (COX-2) inhibition. In order to find more selective COX inhibitors a series of bridged stilbene derivatives ... |
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Organocatalytic asymmetric Friedel-Crafts alkylation/cascade reactions of naphthols and nitroolefins.
Chem. Commun. (Camb.) (22) , 2228-30, (2007) The asymmetric Michael-type Friedel-Crafts reaction of naphthols and nitroolefins promoted by bifunctional thiourea-tertiary amine organocatalysts (up to 95% ee) was investigated; on simply extending the reaction time further cascade reactions could occur to ... |
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Asymmetric epoxidation using a singly-bound supported Katsuki-type (salen)Mn complex.
Chem. Commun. (Camb.) (8) , 886-7, (2002) We have successfully prepared an unsymmetrical analogue of a Katsuki-type salen ligand having a single hydroxyalkyl group at its 6-position, and also its Mn(III) complex; attachment of the complex to a polymer gives a highly enantioselective and recoverable c... |
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Indatraline: synthesis and effect on the motor activity of Wistar rats.
Molecules 16(11) , 9421-38, (2011) A new approach for the synthesis of indatraline was developed using as the key step an iodine(III)-mediated ring contraction of a 1,2-dihydronaphthalene derivative. Behavioral tests were conducted to evaluate the effect of indatraline and of its precursor ind... |
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Initial reactions in the oxidation of 1,2-dihydronaphthalene by Sphingomonas yanoikuyae strains.
Appl. Environ. Microbiol. 62(12) , 4388-94, (1996) The substrate oxidation profiles of Sphingomonas yanoikuyae B1 biphenyl-2,3-dioxygenase and cis-biphenyl dihydrodiol dehydrogenase activities were examined with 1,2-dihydronaphthalene and various cis-diols as substrates. m-Xylene-induced cells of strain B1 ox... |
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Biotransformation of 1,2-dihydronaphthalene and 1,2-dihydroanthracene by rat liver microsomes and purified cytochromes P-450. Formation of arene hydrates of naphthalene and anthracene.
Chem. Res. Toxicol. 6(6) , 808-12, (1993) Both 1,2-dihydronaphthalene and 1,2-dihydroanthracene were hydroxylated at the benzylic (1-) or the allylic (2-) position by rat liver microsomes and purified cytochrome P-450 enzymes to yield "arene hydrates". Two other classes of metabolites were formed, th... |
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Chloroperoxidase from Caldariomyces fumago is active in the presence of an ionic liquid as co-solvent.
Biotechnol. Lett. 26(23) , 1815-9, (2004) Chloroperoxidase from Caldariomyces fumago catalyses the oxidation of 1,2-dihydronaphthalene to (1R,2R)-(+)-dihydroxytetrahydronaphthalene in homogenous citrate buffer/ionic liquid mixtures, using t-butyl hydroperoxide as O2 donor. It tolerates up to 30 (v/v)... |
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Desaturation and oxygenation of 1,2-dihydronaphthalene by toluene and naphthalene dioxygenase.
J. Bacteriol. 177(20) , 5799-805, (1995) Bacterial strains expressing toluene and naphthalene dioxygenase were used to examine the sequence of reactions involved in the oxidation of 1,2-dihydronaphthalene. Toluene dioxygenase of Pseudomonas putida F39/D oxidizes 1,2-dihydronaphthalene to (+)-cis-(1S... |
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Reaction of thallium(III) salts with homoallylic alcohols: ring contraction vs. dimethoxylation.
Molecules 10(11) , 1419-28, (2005) The oxidation of 2-(3,4-dihydronaphthalen-1-yl)-ethanol (1) with a variety of thallium(III) salts was investigated. An indan, formed by a ring contraction reaction, was obtained in good to moderate yields under a variety of reaction conditions: i) thallium tr... |