4-Fluorophenylacetylene
4-Fluorophenylacetylene structure
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Common Name | 4-Fluorophenylacetylene | ||
|---|---|---|---|---|
| CAS Number | 766-98-3 | Molecular Weight | 120.124 | |
| Density | 1.1±0.1 g/cm3 | Boiling Point | 138.6±23.0 °C at 760 mmHg | |
| Molecular Formula | C8H5F | Melting Point | 26-27 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 24.3±15.7 °C | |
| Symbol |
GHS02, GHS07 |
Signal Word | Danger | |
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Sequential one-pot ruthenium-catalyzed azide-alkyne cycloaddition from primary alkyl halides and sodium azide.
J. Org. Chem. 76(7) , 2355-9, (2011) An experimentally simple sequential one-pot RuAAC reaction, affording 1,5-disubstituted 1H-1,2,3-triazoles in good to excellent yields starting from an alkyl halide, sodium azide, and an alkyne, is reported. The organic azide is formed in situ by treating the... |
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Pd-catalyzed coupling reaction on the organic monolayer: Sonogashira reaction on the silicon (111) surfaces. Qu M, et al.
Appl. Surf. Sci. 255(5) , 2608-2612, (2008)
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An OCO3- trianionic pincer tungsten(VI) alkylidyne: rational design of a highly active alkyne polymerization catalyst.
J. Am. Chem. Soc. 134(10) , 4509-12, (2012) Synthesis, characterization, and catalytic alkyne polymerization results for the first trianionic pincer alkylidyne complex, [(t)BuOCO]W≡CC(CH(3))(3)(THF)(2) (6), are described. Complex 6 is a highly active catalyst for the polymerization of acetylenes and ex... |
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Novel regio-and stereoselective dimerization of terminal alkynes catalyzed by rare-earth silylamide. Komeyama K, et al.
Synthesis 7 , 1062-1066, (2004)
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Regioselective One-Pot Synthesis of Isocoumarins and Phthalides from 2-Iodobenzoic Acids and Alkynes by Temperature Control. Kumar MR, et al.
Adv. Synth. Catal. 355(16) , 3221-30, (2013)
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Polyhalogenoheterocyclic compounds. Part 53. Sonogashira reactions of 2, 4, 6-tribromo-3, 5-difluoropyridine. Howardb JAK.
ARKIVOC 11 , 46-55, (2007)
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Intermolecular Gold (I)-Catalyzed Alkyne Carboalkoxylation Reactions for the Multicomponent Assembly of β-Alkoxy Ketones. Schultz DM, et al.
Adv. Synth. Catal. 354(18) , 3451-3455, (2012)
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Bis (μ-iodo) bis ((-)-sparteine) dicopper (I) catalyzed Sonogashira-type reaction under palladium and phosphine-free conditions. Priyadarshini S, et al.
Tetrahedron Lett. 52(14) , 1615-1618, (2011)
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