Cyclohexene
Cyclohexene structure
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Common Name | Cyclohexene | ||
|---|---|---|---|---|
| CAS Number | 110-83-8 | Molecular Weight | 82.144 | |
| Density | 0.8±0.1 g/cm3 | Boiling Point | 85.6±7.0 °C at 760 mmHg | |
| Molecular Formula | C6H10 | Melting Point | -104 °C | |
| MSDS | Chinese USA | Flash Point | -12.2±0.0 °C | |
| Symbol |
GHS02, GHS06, GHS08 |
Signal Word | Danger | |
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Trimetallic magnesium complexes bearing amine-bis(benzotriazole phenolate) derivatives as bifunctional catalysts for ring-opening polymerization and CO2/epoxide coupling.
Chem. Commun. (Camb.) 48(77) , 9628-30, (2012) New trimetallic magnesium complexes were synthesized for bifunctional catalysis. Complex catalysed ε-caprolactone polymerizations in not only a 'living' manner but also in an 'immortal' fashion. Additionally, tri-Mg was active for the coupling of CO(2) with c... |
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Oxidation-resistant acidic resins prepared by partial carbonization as cocatalysts in synthesis of adipic acid.
ACS Appl. Mater. Interfaces 4(8) , 4106-12, (2012) The oxidation-resistant acidic resins are of great importance for the catalytic oxidation systems. In this paper, the oxidatively stable acidic resins are obtained from the cation ion exchange resins (CIERs) through the thermal treatment in N(2) atmosphere. T... |
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Conformational analysis of δ-lactones by DFT calculations: the parent compound and its monomethyl and selected dimethyl derivatives.
Chemistry 19(4) , 1288-302, (2013) The static and dynamic stereochemistry of unsubstituted δ-valerolactone, all monomethylated δ-lactones, and all nongeminally dimethylated δ-lactones was explored with the B3LYP functional and def2-TZVPP basis set. A search strategy was employed which allowed ... |
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Retinal β-ionone ring-salinixanthin interactions in xanthorhodopsin: a study using artificial pigments.
Biochemistry 52(7) , 1290-301, (2013) Xanthorhodopsin (xR) is a retinal protein that contains, in addition to the retinal chromophore, a carotenoid (salinixanthin) that functions as a light-harvesting antenna [Balashov, S. P., et al. (2005) Science 309, 2061-2064]. The center-center distance betw... |
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Syntheses of cellotriose and cellotetraose analogues as transition state mimics for mechanistic studies of cellulases.
Bioorg. Med. Chem. 19 , 3812, (2011) Cellotriose and cellotetraose analogues carrying cyclohexene rings were developed as molecular probes which are expected to mimic the transition state conformation of hydrolysis by cellulases. The cyclohexene ring was placed at the pyranose ring being expecte... |
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Natural orbital Fukui function and application in understanding cycloaddition reaction mechanisms.
Phys. Chem. Chem. Phys. 14(28) , 9890-6, (2012) A new condensed form of the Fukui function, the natural orbital Fukui function (NOFF), is proposed and derived from natural bond orbital occupancy. It is defined as the change in natural bond orbital occupancy upon electronic perturbation (electron addition t... |
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Analysis of α-acyloxyhydroperoxy aldehydes with electrospray ionization-tandem mass spectrometry (ESI-MS(n)).
J. Mass Spectrom. 48(1) , 79-88, (2013) A series of α-acyloxyhydroperoxy aldehydes was analyzed with direct infusion electrospray ionization tandem mass spectrometry (ESI/MS(n)) as well as liquid chromatography coupled with the mass spectrometry (LC/MS). Standards of α-acyloxyhydroperoxy aldehydes ... |
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EPR, 1H and 2H NMR, and reactivity studies of the iron-oxygen intermediates in bioinspired catalyst systems.
Inorg. Chem. 50(12) , 5526-38, (2011) Complexes [(BPMEN)Fe(II)(CH(3)CN)(2)](ClO(4))(2) (1, BPMEN = N,N'-dimethyl-N,N'-bis(2-pyridylmethyl)-1,2-diaminoethane) and [(TPA)Fe(II)(CH(3)CN)(2)](ClO(4))(2) (2, TPA = tris(2-pyridylmethyl)amine) are among the best nonheme iron-based catalysts for bioinspi... |
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Pressure dependent aerosol formation from the cyclohexene gas-phase ozonolysis in the presence and absence of sulfur dioxide: a new perspective on the stabilisation of the initial clusters.
Phys. Chem. Chem. Phys. 14(33) , 11695-705, (2012) The ozonolysis of cyclohexene is studied with respect to the pressure dependent formation of stable gas-phase products and secondary organic aerosol (SOA) as well as the influence of the presence of SO(2). In addition the rate coefficient for the initial reac... |
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Vibrational spectroscopic investigation of 1-pyrrolidino-1-cyclohexene: a comparative density functional study.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 113 , 1-9, (2013) Infrared and Raman spectra of 1-pyrrolidino-1-cyclohexene (1pych) have experimentally been reported in the region of 4000-100 cm(-1). The conformational analysis, optimized geometric parameters, normal mode frequencies and corresponding vibrational assignment... |