2-Isobutyrylcyclohexanone

2-Isobutyrylcyclohexanone Structure
2-Isobutyrylcyclohexanone structure
Common Name 2-Isobutyrylcyclohexanone
CAS Number 39207-65-3 Molecular Weight 168.233
Density 1.0±0.1 g/cm3 Boiling Point 265.9±23.0 °C at 760 mmHg
Molecular Formula C10H16O2 Melting Point 38°C
MSDS Chinese USA Flash Point 98.4±19.6 °C
Symbol GHS07
GHS07
Signal Word Warning

An alternative to the classical α-arylation: the transfer of an intact 2-iodoaryl from ArI(O₂CCF₃)₂.

Angew. Chem. Int. Ed. Engl. 53(42) , 11298-301, (2014)

The α-arylation of carbonyl compounds is generally accomplished under basic conditions, both under metal catalysis and via aryl transfer from the diaryl λ(3)-iodanes. Here, we describe an alternative metal-free α-arylation using ArI(O2CCF3)2 as the source of ...