4-methylthioanisole

4-methylthioanisole Structure
4-methylthioanisole structure
Common Name 4-methylthioanisole
CAS Number 623-13-2 Molecular Weight 138.230
Density 1.0±0.1 g/cm3 Boiling Point 222.7±0.0 °C at 760 mmHg
Molecular Formula C8H10S Melting Point N/A
MSDS Chinese USA Flash Point 85.0±0.0 °C
Symbol GHS07
GHS07
Signal Word Warning

Aerobic oxidation of methyl p-tolyl sulfide catalyzed by a remarkably labile heteroscorpionate RuII-aqua complex, fac-[RuII(H2O)(dpp)(tppm)]2+.

J. Am. Chem. Soc. 125(2) , 308-9, (2003)

fac-[RuII(Cl)(dpp)(L3)]+ (L3 = tris(pyrid-2-yl)methoxymethane (tpmm) = [1A]+ and tris(pyrid-2-yl)pentoxymethane (tppm) = [1B]+ and dpp = di(pyrazol-1-yl)propane) rapidly undergo ligand substitution with water to form fac-[RuII(H2O)(dpp)(L3)]2+ (L3 = tpmm = [2...

Chloroperoxidase and hydrogen peroxide: An efficient system for enzymatic enantioselective sulfoxidations Colonna S, et al.

Tetrahedron Asymmetry 3(1) , 95-106, (1992)