sodium dicyanoaurate(1-)
sodium dicyanoaurate(1-) structure
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Common Name | sodium dicyanoaurate(1-) | ||
|---|---|---|---|---|
| CAS Number | 15280-09-8 | Molecular Weight | 271.99100 | |
| Density | N/A | Boiling Point | 25.7ºC at 760mmHg | |
| Molecular Formula | C2AuN2Na | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | N/A | |
| Symbol |
GHS06 |
Signal Word | Danger | |
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On the origin of asymmetric interactions between permeant anions and the cystic fibrosis transmembrane conductance regulator chloride channel pore.
Biophys. J. 92(4) , 1241-53, (2007) Single channel and macroscopic current recording was used to investigate block of the cystic fibrosis transmembrane conductance regulator (CFTR) Cl(-) channel pore by the permeant anion Au(CN)2(-). Block was 1-2 orders of magnitude stronger when Au(CN)2(-) wa... |
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Cholestatic hepatitis caused by acute gold potassium cyanide poisoning.
J. Toxicol. Clin. Toxicol. 39(7) , 739-43, (2001) Poisoning after oral ingestion of gold potassium cyanide is rarely reported. A case of suicidal ingestion of gold potassium cyanide (potassium dicyanoaurate; CAS# 13967-50-5) is described.A 27-year-old man attempted suicide by ingesting 5 mL gold potassium cy... |
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Contact allergy to gold sodium thiosulfate. A comparative study.
Contact Dermatitis 37(2) , 78-81, (1997) During 1995, we added gold sodium thiosulfate and potassium dicyanoaurate to the patch test standard series. Our purpose was to compare the reactivity of the gold salts, to determine the frequency of contact allergy to gold in our country, to compare our resu... |
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Redox and ligand exchange reactions of potential gold(I) and gold(III)-cyanide metabolites under biomimetic conditions.
J. Inorg. Biochem. 85(1) , 67-76, (2001) Biomimetic pathways for the oxidation of [Au(CN)(2)](-), a gold metabolite, and further cyanation of the gold(III) products to form Au(CN)(4)(-) were investigated using 13C NMR and UV-Visible spectroscopic methods. Hypochlorite ion, an oxidant released during... |
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Determination of cyanide, in urine and gastric content, by electrospray ionization tandem mass spectrometry after direct flow injection of dicyanogold.
Anal. Chim. Acta 651(1) , 81-4, (2009) A rapid and sensitive electrospray ionization tandem mass spectrometric (ESI-MS-MS) procedure was developed for the determination of cyanide (CN(-)). CN(-) in biological fluids was reacted with NaAuCl(4) to produce dicyanogold, Au(CN)(2)(-), which was extract... |
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Glutathionato-S-Gold(III) complexes formed as intermediates in the reduction of auricyanide by glutathione.
J. Inorg. Biochem. 102(3) , 584-93, (2008) The reduction of auricyanide ([Au(CN)(4)](-), a potential gold(III) metabolite of antiarthritic gold(I) compounds), by glutathione (G(-)SH, an anionic biological reductant) proceeds through two intermediates (I(230) and I(290)) which have previously been iden... |
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CFTR: Ligand exchange between a permeant anion ([Au(CN)2]-) and an engineered cysteine (T338C) blocks the pore.
Biophys. J. 91(5) , 1737-48, (2006) Previous attempts to identify residues that line the pore of the cystic fibrosis transmembrane conductance regulator (CFTR) chloride channel have utilized cysteine-substituted channels in conjunction with impermeant, thiol-reactive reagents like MTSET+ and MT... |
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Proton-linked bi- and tri-metallic gold cyanide complexes observed by ESI-MS spectrometry.
J. Inorg. Biochem. 102(3) , 576-83, (2008) Electrospray ionization spectra of potential cyanide-containing gold-drug metabolites revealed additional, weak, unanticipated peaks at approximately twice the mass of the gold(I) and gold(III) cyanide complexes. The exact masses correspond to proton-linked b... |
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[EXAFS study on the stripping mechanism in N263/alkaline cyanide gold solution/sulfuric thiourea system].
Guang Pu Xue Yu Guang Pu Fen Xi 24(6) , 752-5, (2004) Quaternary ammonium salt has strong affinity with gold in cyanide solutions, but it is not readily stripped. Stripping with acidic thiourea solutions and air sparging shows promise. There are some reports on the process of thiourea stripping, but little about... |
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Is local biotransformation the key to understanding the pharmacological activity of salicylates and gold drugs?
Inflamm. Res. 45(12) , 579-82, (1996) It is suggested that some drugs may be converted by inflammatory cells to yield active species. The transformation may be non-enzymatic, although being driven by the enzymatic production of highly reactive species which are normal products of activated leukoc... |