2-(Bromovinyl)Trimethylsilane
2-(Bromovinyl)Trimethylsilane structure
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Common Name | 2-(Bromovinyl)Trimethylsilane | ||
|---|---|---|---|---|
| CAS Number | 41309-43-7 | Molecular Weight | 179.13000 | |
| Density | 1.167 g/mL at 25 °C(lit.) | Boiling Point | 50-51 °C52 mm Hg(lit.) | |
| Molecular Formula | C5H11BrSi | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 85 °F | |
| Symbol |
GHS02, GHS07 |
Signal Word | Warning | |
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Palladium-Catalyzed Cross-Coupling Syntheses of Benzotriazolyl Enynes and a General Route to Enynyl Ketones and Alkynyl Ketones.
J. Org. Chem. 62(23) , 8201-8204, (1997) A new general route to conjugated enynyl ketones was developed based on a two-step procedure. First, palladium-catalyzed cross-coupling reactions of 1-(benzotriazol-1-yl)propargyl ethyl ether (3) and vinyl triflates or vinyl bromides afforded the key intermed... |
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Ligand effects on Negishi couplings of alkenyl halides.
Org. Lett. 13(15) , 3818-21, (2011) Negishi couplings at olefinic centers do not always occur with the anticipated maintenance of stereochemistry. The source of erosion has been traced to the ligand, and a modified method has been developed that solves the stereochemical issue and significantly... |
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Spiro [2.4] hepta-1, 4, 6-triene Billups WE, et al.
J. Am. Chem. Soc. 116(14) , 6463, (1994)
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