Fluoroacetone
Fluoroacetone structure
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Common Name | Fluoroacetone | ||
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| CAS Number | 430-51-3 | Molecular Weight | 76.06960 | |
| Density | 1.054 g/mL at 25 °C(lit.) | Boiling Point | 75 °C(lit.) | |
| Molecular Formula | C3H5FO | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 45 °F | |
| Symbol |
GHS02, GHS06 |
Signal Word | Danger | |
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13C NMR, infrared, solvation and theoretical investigation of the conformational isomerism in 1-haloacetones (X = Cl, Br and I).
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 61(9) , 2221-30, (2005) The solvent dependence of the 13C NMR spectra of chloroacetone (CA), bromoacetone (BA) and iodoacetone (IA) are reported and the 3J(CH) couplings analysed using ab initio calculations and solvation theory. In CA the energy difference (E(cis) - E(gauche)) betw... |
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Lange A, et al.
J. Chem. Soc., Perkin Trans. II 7 , 1343-1350, (1999)
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Organocatalyzed highly enantioselective direct aldol reactions of aldehydes with hydroxyacetone and fluoroacetone in aqueous media: the use of water to control regioselectivity.
Chemistry 13(2) , 689-701, (2007) An organocatalyst prepared from (2R,3R)-diethyl 2-amino-3-hydroxysuccinate and L-proline exhibited high regio- and enantioselectivities for the direct aldol reactions of hydroxyacetone and fluoroacetone with aldehydes in aqueous media. It was found that water... |
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How trifluoroacetone interacts with water.
J. Phys. Chem. A 115(34) , 9493-7, (2011) The rotational spectra of five isotopologues of the molecular adduct 1,1,1-trifluoroacetone-water have been assigned using pulsed-jet Fourier-transform microwave spectroscopy. All rotational transitions appear as doublets, due to the internal rotation of the ... |
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Raman study on conformational equilibria of fluoroacetone in aqueous solutions.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 56A(9) , 1693-701, (2000) The effects of water and heavy water on conformational equilibria of fluoroacetone have been investigated via Raman spectroscopy. Additional Raman bands have been observed in the C-F stretching and the C-C-C symmetric stretching regions for the aqueous soluti... |