![]() [4,4'-Bipyridine] 1,1'-dioxide xhydrate structure
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Common Name | [4,4'-Bipyridine] 1,1'-dioxide xhydrate | ||
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CAS Number | 338950-86-0 | Molecular Weight | 224.21300 | |
Density | N/A | Boiling Point | N/A | |
Molecular Formula | C10H12N2O4 | Melting Point | 220ºC (dec.)(lit.) | |
MSDS | Chinese USA | Flash Point | N/A | |
Symbol |
![]() GHS07 |
Signal Word | Warning |
Experimental electron density study of the supramolecular aggregation between 4,4'-dipyridyl-N,N'-dioxide and 1,4-diiodotetrafluorobenzene at 90 K.
Acta Crystallogr. B 60(Pt 5) , 559-68, (2004) The electron density of the halogen-bonded complex of 4,4'-dipyridyl-N,N'-dioxide (bpNO) with 1,4-diiodotetrafluorobenzene (F(4)dIb) at 90 K has been determined by X-ray diffraction and analysed. The nature of the I.O intermolecular bond connecting the bpNO a... |
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Multi-dimensional transition-metal coordination polymers of 4,4'-bipyridine-N,N'-dioxide: 1D chains and 2D sheets.
Inorg. Chem. 47(19) , 8652-64, (2008) Reaction of 4,4'-bipyridine -N, N' -dioxide (L) with a variety of transition-metal salts in MeOH affords a range of coordination polymer products. For the complexes [FeCl 3(mu-L)] infinity, 1, and ([Cu(L) 2(OHMe) 2(mu-L)].2PF 6. n(solv)) infinity, 2, 1D chain... |
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Constructing terbium co-ordination polymers of 4,4'-bipyridine-N,N'-dioxide by means of diffusion solvent mixtures.
Chemistry 8(9) , 2026-33, (2002) Five different co-ordination polymers of terbium(III) and the bidentate ligand 4,4'-bipyridine-N,N'-dioxide (L), [Tb(L)(CH(3)OH)(NO(3))(3)](infinity) (1), ([Tb(L)(1.5)(NO(3))(3)].CH(2)Cl(2))(infinity) (2), ([Tb(L)(1.5)(NO(3))(3)].CH(3)OH.0.8H(2)O)(infinity) (... |
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Novel 3D, 2D, and 0D first-row coordination compounds with 4,4'-bipyridine-N,N'-dioxide incorporating sulfur-containing anions.
Inorg. Chem. 45(8) , 3287-94, (2006) The reaction of M(S2O6) (M = Cu(II), Ni(II), and Co(II)) with 4,4'-bipyridine-N,N'-dioxide (bpdo) results in the formation of novel 3D, 2D, and mononuclear complexes. Complex 1, {[Cu(H2O)(bpdo)2](S2O6)(H2O)}n, is a 2-D wavelike polymer with the Cu(II) ion loc... |
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Structural versatility and luminescent properties in d(10) metal ion polymers with 1,4-naphthalenedicarboxylate acid and 4,4'-dipyridyl N,N'-dioxide.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 122 , 392-9, (2014) Hydrothermal reactions of d(10) metal ions (Cd(2+) and Zn(2+)) with 1,4-naphthalenedicarboxylate acid (1,4-H2NDC) and 4,4'-dipyridyl N,N'-dioxide (4,4'-dpdo) form two three-dimensional grid-like coordination polymers [Cd2(1,4-NDC)2(4,4'-dpdo)]·H2O 1 and [Zn4(... |
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Host-guest interaction dictated selective adsorption and fluorescence quenching of a luminescent lightweight metal-organic framework toward liquid explosives.
Dalton Trans. 43(40) , 15237-44, (2014) In this article, we report the successful preparation of a Mg-based luminescent MIL-53 metal-organic framework (MOF), namely [Mg2(BDC)2(BPNO)]·2DMF (1) (BDC = 1,4-benzene dicarboxylate, BPNO = 4,4'-dipyridyl-N,N'-dioxide, DMF = N,N-dimethylformamide) in a mix... |