Boron trichloride
Boron trichloride structure
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Common Name | Boron trichloride | ||
|---|---|---|---|---|
| CAS Number | 10294-34-5 | Molecular Weight | 117.170 | |
| Density | 1.4±0.1 g/cm3 | Boiling Point | 12.5±9.0 °C at 760 mmHg | |
| Molecular Formula | BCl3 | Melting Point | −107 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 84 °F | |
| Symbol |
GHS05, GHS06, GHS08 |
Signal Word | Danger | |
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Acute inhalation toxicology of oxalyl chloride.
Am. Ind. Hyg. Assoc. J. 56(1) , 74-6, (1995) The acute inhalation LC50 of oxalyl chloride was determined in rats following a one-hour exposure. Four groups of 10 animals per group were exposed to a concentration range of 462-2233 ppm. One set of six animals was exposed to a concentration of oxalyl chlor... |
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Microwave-assisted synthesis of salicylamide via BCl3 mediated coupling.
J. Comb. Chem. 7(4) , 622-6, (2005) A novel and efficient microwave-assisted, BCl3-mediated coupling reaction to synthesize salicylamide structures from phenols and isocyanates is described. |
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Effect of occupational safety measures on micronucleus frequency in semiconductor workers.
Int. Arch. Occup. Environ. Health 81(4) , 423-8, (2008) To examine whether semiconductor workers exposed to complex mixtures of chemical waste show an increase in genotoxic effects, and, if so, whether occupational safety measures protect these workers.To assess chemical exposure in the workplace, air monitoring o... |
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Theoretical study of the decomposition of BCl3 induced by a H radical.
J. Phys. Chem. A 115(18) , 4786-97, (2011) We report on a theoretical study of the gas-phase decomposition of boron trichloride in the presence of hydrogen radicals using ab initio energetic calculations coupled to TST, RRKM, and VTST-VRC kinetic calculations. In particular, we present an addition-eli... |
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Fragment mode analysis and its application to the vibrational normal modes of boron trichloride-ammonia and boron trichloride-pyridine complexes.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 57(3) , 521-34, (2001) A method for expressing quantitatively the vibrational normal modes of a molecule in a basis set consisting of the normal vibrations (plus translations and rotations) of its constituent fragments is presented. The method is illustrated by describing the vibra... |
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Coordination compounds of boron trichloride; systems with the propyl chlorides.
J. Phys. Colloid Chem. 51(2) , 425-30, (1947)
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Coördination compounds of boron trichloride; systems with methyl chloride and ethyl chloride.
J. Phys. Chem. 50(5) , 422-7, (1946)
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Syntheses of Sceptrins and Nakamuric Acid and Insights into the Biosyntheses of Pyrrole-Imidazole Dimers.
Org. Chem. Front. 2(8) , 978-984, (2015) Sceptrins and nakamuric acid are structurally unique antibiotics isolated from marine sponges. Recent studies suggest that the biosynthesis of these dimeric pyrrole-imidazole alkaloids involves a single-electron transfer (SET)-promoted [2+2] cycloaddition to ... |
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Conversion of F-BODIPYs to Cl-BODIPYs: enhancing the reactivity of F-BODIPYs.
J. Org. Chem. 78(2) , 757-61, (2013) A new method for the synthesis of Cl-BODIPYs from F-BODIPYs is reported, merely requiring treatment of the F-BODIPY with boron trichloride. Cl-BODIPYs are exploited as synthetic intermediates generated in situ for the overall conversion of F-BODIPYs to O- and... |
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Microwave-assisted, boron trichloride mediated acylation of phenols-synthesis of (o-hydroxyaryl)(aryl)methanones and xanthones.
J. Comb. Chem. 8 , 361-367, (2006) A novel and efficient microwave-assisted, BCl(3) mediated coupling reaction to synthesize o-(hydroxyaryl)(aryl)methanone structures from phenols and acyl chlorides is described. This reaction was further incorporated into a two-step synthesis of biologically ... |