Involvement of free nitrenium ions, ion pairs, and preassociation trapping in the reactions of ester derivatives of N-arylhydroxylamines and N-arylhydroxamic acids in …

M Novak, MJ Kahley, J Lin, SA Kennedy…

Index: Journal of Organic Chemistry, , vol. 60, # 25 p. 8294 - 8304

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Citation Number: 60

Abstract

... Scheme 1.2 This is an adequate description of the behavior of the less reactive and more selective ions such as 3h and 3i, but as the ions become more reactive the ion pair 2 must begin to play a role in the hydrolysis chemistry of 1 because the ion will ... 8296 J. Org. Chem., Vol. ...