Iron-catalyzed oxidative coupling of arylboronic acids with benzene derivatives through homolytic aromatic substitution

N Uchiyama, E Shirakawa, R Nishikawa…

Index: Uchiyama, Nanase; Shirakawa, Eiji; Nishikawa, Ryo; Hayashi, Tamio Chemical Communications, 2011 , vol. 47, # 42 p. 11671 - 11673

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Citation Number: 30

Abstract

Fe (OTf) 3–1, 10-phenanthroline catalyzes oxidative coupling of arylboronic acids with benzene derivatives using t-BuOOt-Bu as an oxidant. The reaction proceeds through homolytic aromatic substitution with aryl radicals generated from arylboronic acids and t- BuO˙.