A New Indirect Application of Aggregative Activation: Synthesis of Esters by Cobalt-Catalyzed Carbonylation of Aryl, Heterocyclic, and Vinyl Halides under …

…, J Bodiguel, Y Fort, P Caubere

Index: Marchal, Joel; Bodiguel, Jacques; Fort, Yves; Caubere, Paul Journal of Organic Chemistry, 1995 , vol. 60, # 26 p. 8336 - 8340

Full Text: HTML

Citation Number: 21

Abstract

Sun lamp illuminated alkoxycarbonylation of aryl, heteroaryl, and vinyl halides was performed under atmospheric pressure of CO in the presence of a cobalt catalyst in situ generated from Co (0Ac) z. Illumination through a Pyrex flask was sufficient to catalyze the reaction. This process avoids the use of COZ (CO)~ and excess CHd, which were required in the earlier procedure. A SRN~ mechanism is proposed.

 Related Synthetic Route

~76%

Detail Learn More

~65%

Detail Learn More

~84%

Learn More

~84%

Detail Learn More

~8%

Learn More

~8%

Detail Learn More

~87%

Detail Learn More

~88%

Detail Learn More

~67%

Learn More

~64%

Detail Learn More

~8%

Learn More

~8%

Detail Learn More

~11%

Learn More

~11%

Detail Learn More

~18%

Learn More

~19%

Detail Learn More

~55%

Learn More

~54%

Detail Learn More

~67%

Learn More

~67%

Detail Learn More

~69%

Learn More

~69%

Detail Learn More

~13%

Learn More

~13%

Detail Learn More

~71%

Learn More

~69%

Detail Learn More

~63%

Detail Learn More

~2%

Learn More

~2%

Detail Learn More

~7%

Learn More

~7%

Detail Learn More

~8%

Learn More

~15%

Detail Learn More

~15%

Detail Learn More

~5%

Detail Learn More

~6%

Detail Learn More

~11%

Detail Learn More

~11%

Detail Learn More

~12%

Detail Learn More

~6%

Detail Learn More

~9%

Detail Learn More

~3%

Detail Learn More

~2%

Detail Learn More

~75%

Detail Learn More

~5%

Learn More

~4%

Detail Learn More

~61%

Learn More

~75%

Learn More

~3%

Detail Learn More

~3%

Detail Learn More

~70%

Detail Learn More

~17%

Learn More

~17%

Detail Learn More

~64%

Learn More

~61%

Detail Learn More

~84%

Learn More

~82%

Detail Learn More