| Name | FMOC-L-Aspartic acid β-tert-butyl ester |
|---|---|
| Synonyms |
L-Aspartic acid, N-[(9H-fluoren-9-ylmethoxy)carbonyl]-, 4-(1,1-dimethylethyl) ester
FMOC-L-Asparticacidbeta-tert-butylester 4-tert-Butyl hydrogen N-((9H-fluoren-9-ylmethoxy)carbonyl)-L-aspartate (2S)-2-{[(9H-Fluoren-9-ylmethoxy)carbonyl]amino}-4-[(2-methyl-2-propanyl)oxy]-4-oxobutanoic acid MFCD00037131 FMOC-L-Aspartic acid beta-tert-butyl ester N-α-FMOC-L-aspartic acid β-tert-butyl ester Fmoc-L-aspartic acid 4-tert-butyl ester Fmoc-Asp(OtBu)-OH EINECS 276-251-7 (2S)-4-tert-Butoxy-2-{[(9H-fluoren-9-ylmethoxy)carbonyl]amino}-4-oxobutanoic acid (non-preferred name) 9-fluorenyl-methoxycarbonyl-L-Asp-tert-butyl ester |
| Description | Fmoc-Asp(OtBu)-OH (4-tert-Butyl N-(fluoren-9-ylmethoxycarbonyl)-L-aspartate) is a aspartate derivative containing amine protecting group Fmoc. Fmoc-Asp(OtBu)-OH can be used for peptide synthesis[1]. |
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| Related Catalog | |
| References |
| Density | 1.3±0.1 g/cm3 |
|---|---|
| Boiling Point | 620.8±55.0 °C at 760 mmHg |
| Melting Point | 148-150 °C (dec.) |
| Molecular Formula | C23H25NO6 |
| Molecular Weight | 411.448 |
| Flash Point | 329.3±31.5 °C |
| Exact Mass | 411.168182 |
| PSA | 101.93000 |
| LogP | 5.16 |
| Vapour Pressure | 0.0±1.9 mmHg at 25°C |
| Index of Refraction | 1.576 |
| Storage condition | 2~8°C |
| Personal Protective Equipment | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
|---|---|
| Hazard Codes | Xi: Irritant; |
| Risk Phrases | R36/37/38 |
| Safety Phrases | S24/25 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | 3 |
| HS Code | 2924299090 |
|
~62%
71989-14-5 |
| Literature: Nowshuddin, Shaik; Rao; Reddy, A. Ram Synthetic Communications, 2009 , vol. 39, # 11 p. 2022 - 2031 |
|
~78%
71989-14-5 |
| Literature: Schoen, Istvan; Kisfaludy, Lajos Synthesis, 1986 , # 4 p. 303 - 305 |
|
~62%
71989-14-5 |
| Literature: Henklein, Peter; Heyne, Hans-Ulrich; Halatsch, Wolf-Rainer; Niedrich, Hartmut Synthesis, 1987 , # 2 p. 166 - 167 |
|
~68%
71989-14-5 |
| Literature: Echner, Hartmut; Voelter, Wolfgang Liebigs Annalen der Chemie, 1988 , p. 1095 - 1098 |
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~%
71989-14-5 |
| Literature: Journal of Organic Chemistry, , vol. 77, # 23 p. 10575 - 10582 |
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~%
71989-14-5 |
| Literature: Synthesis, , # 2 p. 166 - 167 |
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~%
71989-14-5
Detail
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| Literature: Synthesis, , # 7 p. 571 - 572 |
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~%
71989-14-5 |
| Literature: Tetrahedron Letters, , vol. 34, # 2 p. 323 - 326 |
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~%
71989-14-5 |
| Literature: Synthesis, , # 2 p. 166 - 167 |
| Precursor 8 | |
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| DownStream 10 | |
| HS Code | 2924299090 |
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| Summary | 2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0% |