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358-72-5

358-72-5 structure
358-72-5 structure
  • Name: GAMMA GAMMA-DIMETHYLALLYL PYROPHOSPHATE&
  • Chemical Name: prenyl diphosphate
  • CAS Number: 358-72-5
  • Molecular Formula: C5H12O7P2
  • Molecular Weight: 246.09200
  • Catalog: Research Areas Metabolic Disease
  • Create Date: 2016-08-26 03:27:50
  • Modify Date: 2024-01-02 12:44:28
  • DMAPP (Dimethylallyl pyrophosphate) is an isoprenoid precursor. DMAPP, as an isomer of isopentenyl pyrophosphate (IPP), exists in virtually all life forms[1].

Name prenyl diphosphate
Synonyms delta2-Isopentenyl diphosphate
Prenyl diphosphate
2-Isopentenyl diphosphate
dimethylallyl-PPi
dimethylallylpyrophosphate
dimethylallyl-diphosphate
3,3-dimethylallyl pyrophosphate
3-methylbut-2-enyl phosphono hydrogen phosphate
Description DMAPP (Dimethylallyl pyrophosphate) is an isoprenoid precursor. DMAPP, as an isomer of isopentenyl pyrophosphate (IPP), exists in virtually all life forms[1].
Related Catalog
In Vitro DMAPP (Dimethylallyl pyrophosphate) is an isoprenoid precursor. DMAPP is a product of both the mevalonate pathway and the MEP pathway of isoprenoid precursor biosynthesis. DMAPP is an isomer of isopentenyl pyrophosphate (IPP) and exists in virtually all life forms. The enzyme isopentenyl pyrophosphate isomerase catalyzes isomerization between DMAPP and IPP[1]
References

[1]. Wang W, et al. Bioorganometallic chemistry with IspG and IspH: structure, function, and inhibition of the [Fe(4)S(4)] proteins involved in isoprenoid biosynthesis. Angew Chem Int Ed Engl. 2014;53(17):4294-4310.

Density 1.557g/cm3
Boiling Point 417ºC at 760mmHg
Molecular Formula C5H12O7P2
Molecular Weight 246.09200
Flash Point 206ºC
Exact Mass 246.00600
PSA 132.91000
LogP 1.17890
Hazard Codes T: Toxic;
Risk Phrases 10-23/24/25-39/23/24/25
Safety Phrases 7-16-36/37-45
RIDADR UN 1230 3/PG 2
HS Code 2905290000

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Literature: Takagi, Motoki; Kaneda, Kazuhide; Shimizu, Tomohiro; Hayakawa, Yoichi; Seto, Haruo; Kuzuyama, Tomohisa Bioscience, Biotechnology and Biochemistry, 2004 , vol. 68, # 1 p. 132 - 137

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Literature: Dixit, Vyas M.; Laskovics, F. Mark; Noall, Wendy I.; Poulter, C. Dale Journal of Organic Chemistry, 1981 , vol. 46, # 9 p. 1967 - 1969

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Literature: Davisson, V. Jo; Woodside, Andrew B.; Neal, Timothy R.; Stremler, Kay E.; Muehlbacher, Manfred; Poulter, C. Dale Journal of Organic Chemistry, 1986 , vol. 51, # 25 p. 4768 - 4779

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Literature: Dixit, Vyas M.; Laskovics, F. Mark; Noall, Wendy I.; Poulter, C. Dale Journal of Organic Chemistry, 1981 , vol. 46, # 9 p. 1967 - 1969

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Literature: Wang, Weixue; Wang, Ke; Liu, Yi-Liang; No, Joo-Hwan; Li, Jikun; Nilges, Mark J.; Oldfield, Eric Proceedings of the National Academy of Sciences of the United States of America, 2010 , vol. 107, # 10 p. 4522 - 4527

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Literature: Eggerer,H. Chemische Berichte, 1961 , vol. 94, p. 177 - 185

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Literature: Xiao, Youli; Chang, Wei-Chen; Liu, Hung-Wen; Liu, Pinghua Organic Letters, 2011 , vol. 13, # 21 p. 5912 - 5915

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Literature: Xiao, Youli; Chang, Wei-Chen; Liu, Hung-Wen; Liu, Pinghua Organic Letters, 2011 , vol. 13, # 21 p. 5912 - 5915

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Literature: Chen, Mo; Poulter, C. Dale Biochemistry, 2010 , vol. 49, # 1 p. 207 - 217
HS Code 2905290000
Summary 2905290000 unsaturated monohydric alcohols。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%