4-Benzoylbenzonitrile structure
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Common Name | 4-Benzoylbenzonitrile | ||
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CAS Number | 1503-49-7 | Molecular Weight | 207.22700 | |
Density | 1.19g/cm3 | Boiling Point | 377ºC at 760mmHg | |
Molecular Formula | C14H9NO | Melting Point | 110-114 °C(lit.) | |
MSDS | Chinese USA | Flash Point | 181.8ºC | |
Symbol |
GHS07 |
Signal Word | Warning |
Name | 4-cyanobenzophenone |
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Synonym | More Synonyms |
Density | 1.19g/cm3 |
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Boiling Point | 377ºC at 760mmHg |
Melting Point | 110-114 °C(lit.) |
Molecular Formula | C14H9NO |
Molecular Weight | 207.22700 |
Flash Point | 181.8ºC |
Exact Mass | 207.06800 |
PSA | 40.86000 |
LogP | 2.78928 |
Vapour Pressure | 6.95E-06mmHg at 25°C |
Index of Refraction | 1.616 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 20/21/22 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Harmful if inhaled. May cause respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 1503-49-7: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 109 - 112 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C14H9NO Molecular Weight: 207.23 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents, strong bases, strong reducing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Will not occur. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 1503-49-7 unlisted. LD50/LC50: Not available. Carcinogenicity: 4-Cyanobenzophenone - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. Safety Phrases: S 36/37 Wear suitable protective clothing and gloves. WGK (Water Danger/Protection) CAS# 1503-49-7: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 1503-49-7 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 1503-49-7 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
Symbol |
GHS07 |
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Signal Word | Warning |
Hazard Statements | H302-H312-H315-H319-H332-H335 |
Precautionary Statements | P261-P280-P305 + P351 + P338 |
Personal Protective Equipment | dust mask type N95 (US);Eyeshields;Gloves |
Hazard Codes | Xn: Harmful; |
Risk Phrases | R20/21/22 |
Safety Phrases | S26-S36 |
RIDADR | 3439 |
WGK Germany | 3 |
Packaging Group | III |
Hazard Class | 6.1 |
HS Code | 2926909090 |
Precursor 10 | |
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DownStream 10 | |
HS Code | 2926909090 |
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Summary | HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0% |
Electrochemical t-Butylation of Some Aromatic Ketones. Kristensen LH and Lund H.
Acta Chem. Scand. B 33 , 735-741, (1979)
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Electrochemically induced aromatic nucleophilic substitution. Pinson J and Saveant JM.
J. Am. Chem. Soc. 100(5) , 1506-1510, (1978)
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Mechanistic approach to the sensitization process of aromatic ketones in the isomerization between norbornadiene and quadricyclane. Arai T, et al.
Bull. Chem. Soc. Jpn. 60(8) , 2937-2943, (1987)
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4-benzoylbenzonitrile |
EINECS 216-126-6 |
MFCD00016382 |
4-Cyanobenzophenone |