(Triphenylphosphoranylidene)acetaldehyde
(Triphenylphosphoranylidene)acetaldehyde structure
|
Common Name | (Triphenylphosphoranylidene)acetaldehyde | ||
|---|---|---|---|---|
| CAS Number | 2136-75-6 | Molecular Weight | 304.32 | |
| Density | 1.2±0.1 g/cm3 | Boiling Point | 486.9±47.0 °C at 760 mmHg | |
| Molecular Formula | C20H17OP | Melting Point | 185-188 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 248.3±29.3 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
Use of (Triphenylphosphoranylidene)acetaldehyde2-(Triphenylphosphoranylidene)acetaldehyde is a biochemical reagent that can be used as a biological material or organic compound for life science related research. |
This table lists Chinese names, IUPAC names and various aliases of this chemical substance.
| Name | 2-(Triphenylphosphoranylidene)acetaldehyde |
|---|---|
| Synonym | More Synonyms |
This table contains bioactivity, target information and biological‑assay experimental data of this compound.
| Description | 2-(Triphenylphosphoranylidene)acetaldehyde is a biochemical reagent that can be used as a biological material or organic compound for life science related research. |
|---|---|
| Related Catalog | |
| In Vitro | (Formylmethylene)triphenylphosphorane 用作 Wittig 试剂。也用作医药中间体。用作有机合成、农药的原料。 |
This table shows physicochemical parameters including melting point, boiling point, density, solubility and optical rotation. Missing data is marked as N/A.
| Density | 1.2±0.1 g/cm3 |
|---|---|
| Boiling Point | 486.9±47.0 °C at 760 mmHg |
| Melting Point | 185-188 °C(lit.) |
| Molecular Formula | C20H17OP |
| Molecular Weight | 304.32 |
| Flash Point | 248.3±29.3 °C |
| Exact Mass | 304.101715 |
| PSA | 26.88000 |
| LogP | 3.80 |
| Vapour Pressure | 0.0±1.2 mmHg at 25°C |
| Index of Refraction | 1.615 |
| InChIKey | CQCAYWAIRTVXIY-UHFFFAOYSA-N |
| SMILES | O=CC=P(c1ccccc1)(c1ccccc1)c1ccccc1 |
| Storage condition | Keep Cold |
| Stability | Stable. Combustible. Incompatible with strong oxidizing agents. |
This table provides MSDS information including hazard classification, first‑aid, fire‑fighting, spill handling, operation and storage instructions.
This table covers safety warnings, protective measures, incompatible substances and disposal guidelines for this compound.
| Symbol |
GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H315-H319-H335 |
| Precautionary Statements | P261-P305 + P351 + P338 |
| Personal Protective Equipment | dust mask type N95 (US);Eyeshields;Gloves |
| Hazard Codes | Xi: Irritant; |
| Risk Phrases | R36/37/38 |
| Safety Phrases | S26-S36 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | 3 |
| HS Code | 2931900090 |
This table presents publicly reported synthetic routes, reaction conditions, reactants and product information of the compound.
|
~76%
(Triphenylphosp... CAS#:2136-75-6 |
| Literature: Schmidt, Anastasia; Hilt, Gerhard Organic Letters, 2013 , vol. 15, # 11 p. 2708 - 2711 |
|
~51%
(Triphenylphosp... CAS#:2136-75-6 |
| Literature: Wube, Abraham A.; Huefner, Antje; Thomaschitz, Christina; Blunder, Martina; Kollroser, Manfred; Bauer, Rudolf; Bucar, Franz Bioorganic and Medicinal Chemistry, 2011 , vol. 19, # 1 p. 567 - 579 |
|
~%
(Triphenylphosp... CAS#:2136-75-6 |
| Literature: maruta, Yoshihiko; Fukushi, Yukiharu; Ohkawa, Kaori; Nakanishi, Yuko; Tahara, Satoshi; Mizutani, Junya Phytochemistry (Elsevier), 1995 , vol. 38, # 5 p. 1169 - 1174 |
|
~79%
(Triphenylphosp... CAS#:2136-75-6 |
| Literature: Bestmann, Hans Juergen; Roth, Kurt; Ettlinger, Manfred Chemische Berichte, 1982 , vol. 115, # 1 p. 161 - 171 |
|
~%
(Triphenylphosp... CAS#:2136-75-6 |
| Literature: Synthesis, , # 5 p. 364 - 367 |
|
~%
(Triphenylphosp... CAS#:2136-75-6 |
| Literature: Chemische Berichte, , vol. 117, # 4 p. 1561 - 1571 |
|
~%
(Triphenylphosp... CAS#:2136-75-6 |
| Literature: Journal of the Chemical Society. Perkin Transactions 2, , # 7 p. 1287 - 1288 |
|
~%
(Triphenylphosp... CAS#:2136-75-6 |
| Literature: Bulletin des Societes Chimiques Belges, , vol. 73, p. 921 - 943 |
![Phosphonium, [2-(dimethylamino)ethenyl]triphenyl-, chloride (1:1) structure](https://image.chemsrc.com/caspic/249/90601-11-9.png)
This table lists upstream starting materials and downstream derivative products related to this chemical.
| Precursor 8 | |
|---|---|
| DownStream 9 | |
CAS#:110905-37-8
CAS#:557-48-2
CAS#:49678-08-2
CAS#:3913-81-3
CAS#:104-55-2
CAS#:14371-10-9
CAS#:28823-16-7
CAS#:29343-64-4![3-[4-(3-oxoprop-1-enyl)phenyl]prop-2-enal structure](https://image.chemsrc.com/caspic/410/3049-37-4.png)
CAS#:3049-37-4This table shows customs‑related data including HS‑code, tariff and regulatory conditions for import and export.
| HS Code | 2931900090 |
|---|---|
| Summary | 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0% |
This table lists relevant public references with title, journal and publication metadata for this compound.
|
Total synthesis of borrelidin.
J. Org. Chem. 72 , 2744, (2007) The total synthesis of borrelidin has been achieved. The best feature of our synthetic route is macrocyclization at C11-C12 for the construction of an 18-membered ring after esterification between two... |
|
|
First total synthesis and structural reassignment of (-)-aplysiallene.
Org. Lett. 9 , 3703, (2007) The first total synthesis of (-)-aplysiallene has been completed in 16 steps and features a key sequential Mukaiyama aerobic oxidative cyclization to prepare the fused bis-THF core. The original stere... |
|
|
H.J. Bestmann et al.
Angew. Chem. Int. Ed. Engl. 91 , 748, (1979)
|
This table collects all English aliases, systematic names and CAS‑related synonyms of the compound.
| Ph3P=CH-CHO |
| Trippett's reagent |
| (Formylmethylene)triphenylphosphorane |
| (Triphenylphosphoranylidene)acetaldehyde |
| 2-[Methylene(diphenyl)phosphoranyl]benzaldehyde |
| triphenylphosphoranylideneacetaldehyde |
| EINECS 218-375-6 |
| MFCD00006994 |
This section contains frequently‑asked‑questions about this compound, including basic parameters, properties, storage conditions and corresponding answers.
| Q: What is the LogP of 2-(Triphenylphosphoranylidene)acetaldehyde? |
| A: LogP of 2-(Triphenylphosphoranylidene)acetaldehyde is 3.80. |
| Q: What is the molecular weight of 2-(Triphenylphosphoranylidene)acetaldehyde? |
| A: Molecular weight of 2-(Triphenylphosphoranylidene)acetaldehyde is 304.32. |
| Q: What are the upstream materials of 2-(Triphenylphosphoranylidene)acetaldehyde? |
| A: Related upstream materials(CAS) of 2-(Triphenylphosphoranylidene)acetaldehyde: 1779-49-3;109-94-4;107-20-0;603-35-0;62942-43-2;19493-09-5;90601-11-9;2032-35-1. |
| Q: What is the InChIKey of 2-(Triphenylphosphoranylidene)acetaldehyde? |
| A: InChIKey of 2-(Triphenylphosphoranylidene)acetaldehyde is CQCAYWAIRTVXIY-UHFFFAOYSA-N. |
| Q: What is the CAS number of 2-(Triphenylphosphoranylidene)acetaldehyde? |
| A: CAS number of 2-(Triphenylphosphoranylidene)acetaldehyde is 2136-75-6. |
| Q: What is the molecular formula of 2-(Triphenylphosphoranylidene)acetaldehyde? |
| A: Molecular formula of 2-(Triphenylphosphoranylidene)acetaldehyde is C20H17OP. |
| Q: What is the boiling point of 2-(Triphenylphosphoranylidene)acetaldehyde? |
| A: Boiling point of 2-(Triphenylphosphoranylidene)acetaldehyde is 486.9±47.0 °C at 760 mmHg. |
| Q: What is the SMILES notation of 2-(Triphenylphosphoranylidene)acetaldehyde? |
| A: SMILES notation of 2-(Triphenylphosphoranylidene)acetaldehyde is O=CC=P(c1ccccc1)(c1ccccc1)c1ccccc1. |
| Q: What are the storage conditions for 2-(Triphenylphosphoranylidene)acetaldehyde? |
| A: Storage conditions for 2-(Triphenylphosphoranylidene)acetaldehyde: Keep Cold. |
| Q: What are the uses of 2-(Triphenylphosphoranylidene)acetaldehyde? |
| A: Main uses of 2-(Triphenylphosphoranylidene)acetaldehyde: 2-(Triphenylphosphoranylidene)acetaldehyde is a biochemical reagent that can be used as a biological material or organic compound for life science related research. |
This table lists manufacturers and suppliers of this compound, including vendor names and product supply reference information.
| Shanghai Nianxing Industrial Co., Ltd |
| Dayang Chem (Hangzhou) Co., Ltd. |
| Henan Tianfu Chemical Co., Ltd. |