Benzenesulfonylchloride, 2,4-dichloro-5-methyl-

Modify Date: 2024-01-12 09:58:37

Benzenesulfonylchloride, 2,4-dichloro-5-methyl- Structure
Benzenesulfonylchloride, 2,4-dichloro-5-methyl- structure
Common Name Benzenesulfonylchloride, 2,4-dichloro-5-methyl-
CAS Number 28286-86-4 Molecular Weight 259.53700
Density 1.56g/cm3 Boiling Point 333.2ºC at 760mmHg
Molecular Formula C7H5Cl3O2S Melting Point 67-72 °C
MSDS USA Flash Point 155.3ºC

 Names

Name 2,4-dichloro-5-methylbenzenesulfonyl chloride
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.56g/cm3
Boiling Point 333.2ºC at 760mmHg
Melting Point 67-72 °C
Molecular Formula C7H5Cl3O2S
Molecular Weight 259.53700
Flash Point 155.3ºC
Exact Mass 257.90800
PSA 42.52000
LogP 4.31010
Vapour Pressure 0.000268mmHg at 25°C
Index of Refraction 1.571

 MSDS

Name: 2 4-Dichloro-5-methylbenzenesulfonyl chloride Material Safety Data Sheet
Synonym: m-Toluenesulfonyl chloride, 4,6-dichloro-; 2,4-Dichlorotoluene-5-sulfochloride
CAS: 28286-86-4
Section 1 - Chemical Product MSDS Name:2 4-Dichloro-5-methylbenzenesulfonyl chloride Material Safety Data Sheet
Synonym:m-Toluenesulfonyl chloride, 4,6-dichloro-; 2,4-Dichlorotoluene-5-sulfochloride

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
28286-86-4 2,4-Dichloro-5-methylbenzenesulfonyl c > 95 248-938-1
Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Chronic exposure may cause effects similar to those of acute exposure.

Section 4 - FIRST AID MEASURES
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation. Do not get water inside containers.

Section 7 - HANDLING and STORAGE
Handling:
Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing.
Keep container tightly closed. Do not ingest or inhale. Do not allow contact with water. Use only in a chemical fume hood. Discard contaminated shoes. Keep from contact with moist air and steam.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area. Store protected from moisture.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 28286-86-4: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Crystalline powder
Color: off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 67-72 deg C
Autoignition Temperature: Not available.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C7H5Cl3O2S
Molecular Weight: 259.54

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Moisture sensitive. Material hydrolyzes in contact with moisture/water releasing toxic and corrosive fumes of hydrogen chloride and aqueous hydrochloric acid.
Conditions to Avoid:
Dust generation, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 28286-86-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2,4-Dichloro-5-methylbenzenesulfonyl chloride - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 28286-86-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 28286-86-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 28286-86-4 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes C:Corrosive;
Risk Phrases R34
Safety Phrases S45-S36/37/39-S26
RIDADR 1760
Packaging Group II
Hazard Class 8
HS Code 2904909090

 Customs

HS Code 2904909090
Summary HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

 Synonyms

F1967-0681
MFCD00044016
2,4,5-TRIAMINO-6-CHLORO PYRIMIDNE
EINECS 248-938-1
2,4-Dichloro-5-methylbenzenesulfonyl chloride
2,4-dichloro-5-methylbenzene-1-sulfonyl chloride
2,4-dichloro-5-methylbenzene sulfonylchloride
4,6-Dichlor-toluol-3-sulfonylchlorid
2,4-dichloro-5-methylphenylsulfonyl chloride
4,6-dichloro-toluene-3-sulfonyl chloride
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