2-Naphthyl trifluoromethanesulfonate

2-Naphthyl trifluoromethanesulfonate Structure
2-Naphthyl trifluoromethanesulfonate structure
Common Name 2-Naphthyl trifluoromethanesulfonate
CAS Number 3857-83-8 Molecular Weight 276.23200
Density 1.493g/cm3 Boiling Point 343.8ºC at 760 mmHg
Molecular Formula C11H7F3O3S Melting Point 30-32ºC(lit.)
MSDS Chinese USA Flash Point >230 °F
Symbol GHS05
GHS05
Signal Word Danger

Palladium-catalyzed conversion of aryl and vinyl triflates to bromides and chlorides.

J. Am. Chem. Soc. 132 , 14076, (2010)

The palladium-catalyzed conversion of aryl and vinyl triflates to aryl and vinyl halides (bromides and chlorides) has been developed using dialkylbiaryl phosphine ligands. A variety of aryl, heteroaryl, and vinyl halides can be prepared via this method in goo...

Regiochemical control and suppression of double bond isomerization in the Heck arylation of 1-(methoxycarbonyl)-2, 5-dihydropyrrole. Sonesson C, et al.

J. Org. Chem. 61(14) , 4756-4763, (1996)

Influence of the catalyst on the Pd0-mediated reactions of BrZnCH(CH3) COOtBu with vinyl and aryl triflates. Orsini F, et al.

J. Organomet. Chem. 367(3) , 375-382, (1989)