tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite

Modify Date: 2024-01-03 21:41:15

tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite Structure
tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite structure
Common Name tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite
CAS Number 66470-81-3 Molecular Weight 532.06300
Density 1.69 g/mL at 25ºC(lit.) Boiling Point 130ºC(lit.)
Molecular Formula C9H3F18O3P Melting Point N/A
MSDS Chinese USA Flash Point 44.5ºC
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name tris(1,1,1,3,3,3-hexafluoropropan-2-yl) phosphite
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.69 g/mL at 25ºC(lit.)
Boiling Point 130ºC(lit.)
Molecular Formula C9H3F18O3P
Molecular Weight 532.06300
Flash Point 44.5ºC
Exact Mass 531.95300
PSA 41.28000
LogP 6.74270
Index of Refraction n20/D 1.300(lit.)

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi
Risk Phrases R36/37/38
Safety Phrases S26;S36
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2920901900

 Synthetic Route

~97%

tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite Structure

tris(1,1,1,3,3,...

CAS#:66470-81-3

Literature: Mironov, V.F.; Konovalova, I.V. Russian Journal of General Chemistry, 1993 , vol. 63, # 11.2 p. 1760 - 1763 Zhurnal Obshchei Khimii, 1993 , vol. 63, # 11 p. 2537 - 2541

 Precursor & DownStream

Precursor  1

DownStream  1

 Customs

HS Code 2920901900
Summary 2920901900 VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

 Articles5

More Articles
Solid phase synthesis of oligoribonucleotides using the 1-[(2-chloro-4-methyl)phenyl]-4-methoxypiperidin-4-yl (Ctmp) group for the protection of the 2'-hydroxy functions and the H-phosphonate approach.

Nucleic Acids Res. 17(10) , 3689-97, (1989)

The solid phase synthesis of oligoribonucleotides using the H-phosphonate approach and the 1-[(2-chloro-4-methyl)phenyl]-4-methoxypiperidin-4-yl (Ctmp) and dimethoxytrityl (DMTr) groups, respectively,...

Use of new phosphonylating and coupling agents in the synthesis of oligodeoxyribonucleotides via the H-phosphonate approach.

Nucleic Acids Res. 18(11) , 3327-31, (1990)

New phosphonylating and coupling agents for the synthesis of oligodeoxyribonucleotides via H-phosphonate approach have been developed. Tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite, prepared by the ...

Stereoselective propargylation mediated by a chiral metal cluster: reactions of [(propargylium)Co2 (CO)5{P(OR)3}][BF4] with carbon nucleophiles. Caffyn AJM and Nicholas KM.

J. Am. Chem. Soc. 115(14) , 6438-6439, (1993)

 Synonyms

[(CF3)2CHO]3P
Tris[2,2,2-trifluoro-1-(trifluoromethyl)ethyl] phosphite
tris(1,1,1,3,3,3-hexafluoroisopropyl)phosphite
MFCD00192561
P(OiC3HF6)3
Tris(1,1,1,3,3,3-hexafluoro-2-propyl)phosphite
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