三正丙胺

三正丙胺用途

【用途一】
用于制药物、农药、橡胶和纤维加工助剂等
【用途二】
有机合成原料。用于合成全氟化人造血浆和石油化工季铵分子筛催化剂。在激光技术上也有重要用途。
【用途三】
溶剂。有机合成原料,合成全氟化人造血浆和石油化工季铵分子筛催化剂。在激光技术上也有重要用途。

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三正丙胺名称

[ CAS 号 ]:
102-69-2

[ 中文名 ]:
三正丙胺

[ 英文名 ]:
Tripropylamine

[中文别名 ]:

三丙胺

[英文别名 ]:

N,N-Dipropyl-1-propanamine
Tripropyl orthoformate
EINECS 203-047-7
propyl orthoformate
Tripropylamine
tri-n-propoxymethane
MFCD00009363
Orthoformic Acid Tripropyl Ester
tri-n-Propyl orthoformate
Tripropoxymethane

三正丙胺物理化学性质

[ 密度 ]:
0.753 g/mL at 25 °C(lit.)

[ 沸点 ]:
155-158 °C(lit.)

[ 熔点 ]:
−93.5 °C(lit.)

[ 分子式 ]:
C₉H₂₁N

[ 分子量 ]:
143.27000

[ 闪点 ]:
98 °F

[ 精确质量 ]:
143.16700

[ PSA ]:
3.24000

[ LogP ]:
2.51840

[ 外观性状 ]:
无色至似鱼的液体

[ 蒸汽密度 ]:
4.9 (vs air)

[ 蒸汽压 ]:
2.66mmHg at 25°C

[ 折射率 ]:
n20/D 1.416(lit.)

[ 储存条件 ]:
库房通风低温干燥,与氧化剂、酸类分开存放

[ 稳定性 ]:
Stable. Incompatible with acids, oxidizing agents. Protect from moisture. Flammable.

[ 水溶解性 ]:
2.6 g/L (20 ºC)

三正丙胺MSDS

三正丙胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TX1575000

CHEMICAL NAME :: 1-Propanamine, N,N-dipropyl-

CAS REGISTRY NUMBER :: 102-69-2

LAST UPDATED :: 199710

DATA ITEMS CITED :: 9

MOLECULAR FORMULA :: C9-H21-N

MOLECULAR WEIGHT :: 143.31

WISWESSER LINE NOTATION :: 3N3&3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 96 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 5100 mg/m3/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,118,1982

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 3800 mg/m3/2H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,118,1982

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 570 uL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: 5100 mg/m3

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 14,80,1975

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: 740 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 14,80,1975

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三正丙胺安全信息

[ 符号 ]:

GHS02, GHS05, GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H226-H301 + H311 + H331-H314-H335-H412

[ 警示性声明 ]:
P261-P273-P280-P301 + P310-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
T:Toxic

[ 风险声明 (欧洲) ]:
R10;R21;R23/25;R34;R52/53

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45-S16

[ 危险品运输编码 ]:
UN 2260 3/PG 3

[ WGK德国 ]:
2

[ RTECS号 ]:
TX1575000

[ 包装等级 ]:
III

[ 危险类别 ]:
3

[ 海关编码 ]:
29211980

三正丙胺合成路线

三正丙胺上下游产品

三正丙胺上游产品

三正丙胺下游产品

三正丙胺制备

以正丙醇为原料在Ni-Cu-Al2O3催化剂作用下，脱氢生成丙醛，然后与氨加成，脱水、加氢生成丙胺，再经反复脱水、加氢生成二丙胺和三丙胺。反应温度为（210±10）℃，压力为396.66kPa。正丙醇空速为0.25-0.51L/L·h-1。原料配比为醇：氨：氢＝4：2：4。正丙醇转化率为75%-83%，二、三丙胺总产率为75%-80%，其中二丙胺37%-41%，三丙胺35%-40%。原料消耗定额：丙醇3500kg/t、氨500kg/t、氢气1200m3。

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三正丙胺海关

[ 海关编码 ]: 29211980

三正丙胺文献

A Novel Electrochemiluminescence Immunosensor for the Analysis of HIV-1 p24 Antigen Based on P-RGO@Au@Ru-SiO₂ Composite.

ACS Appl. Mater. Interfaces 7 , 24438-45, (2015)

Ru(bpy)3(2+)-doped silica (Ru-SiO2) nanoparticles and gold-nanoparticle-decorated graphene (P-RGO@Au) were combined to form a P-RGO@Au@Ru-SiO2 composite. The composite was used to develop a novel sand...

Investigation of the structure-selectivity relationships and van't Hoff analysis of chromatographic stereoisomer separations of unusual isoxazoline-fused 2-aminocyclopentanecarboxylic acids on Cinchona alkaloid-based chiral stationary phases.

J. Chromatogr. A. 1384 , 67-75, (2015)

The enantiomers of four unusual, rather rigid isoxazoline-fused 2-aminocyclopentanecarboxylic acids were directly separated on a quinine- or a quinidine-based zwitterionic ion-exchanger as chiral sele...

Comparing ion-pairing reagents and counter anions for ion-pair reversed-phase liquid chromatography/electrospray ionization mass spectrometry analysis of synthetic oligonucleotides.

Rapid Commun. Mass Spectrom. 29 , 2402-10, (2015)

Ion-pair reversed-phase liquid chromatography/electrospray ionization mass spectrometry (IP-RP-LC/ESI-MS) has been widely used for the quality control of oligonucleotides. However, researchers are sti...

更多文献

三正丙胺

三正丙胺用途

三正丙胺名称

三正丙胺物理化学性质

三正丙胺MSDS

详细MSDS(安全技术说明书)

三正丙胺毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

三正丙胺安全信息

三正丙胺合成路线

详细合成路线

三正丙胺上下游产品

三正丙胺上游产品

三正丙胺下游产品

三正丙胺制备

三正丙胺海关

三正丙胺文献

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