水杨酸乙酯
水杨酸乙酯用途
用作硝基纤维素的溶剂,也用于香料及有机合成
【用途二】
用于调制日用皂用香精,也用于制药
【用途三】
可用入金合欢、刺槐、依兰、铃兰及其他甜花香型。可少量用于香皂香精中,如在香薇型中作增甜剂。在牙膏和口腔用品中可代替或修饰其甲酯香气与香味。国外也用于食用香精,如欧黑莓、黑茶藨子、圆醋栗、悬钩子、草莓及其他果香和沙士型等香精中。
【用途四】
GB 2760—96规定为暂时允许使用的食用香料。主要用于调制人造桂皮油和黑莓、黑醋栗及草莓等浆果型香精。
【用途五】
用于有机合成或配制香料,也用作溶剂。
【用途六】
溶剂,有机合成,制造人造香料。
水杨酸乙酯名称
[ CAS 号 ]:
118-61-6
[ 中文名 ]:
水杨酸乙酯
[ 英文名 ]:
Ethyl salicylate
[中文别名 ]:
[英文别名 ]:
- ethyl 2-hydroxybenzoate
- ethyl salicilate
- Salotan
- salicylicether
- Ethyl o-hydroxybenzoate
- Ethyl salicylate
- ethyl 2-hydroxy-benzoate
- Benzoic acid, 2-hydroxy-, ethyl ester
- salicylic acid ethyl ester
- 2-Hydroxybenzoic acid ethyl ester
水杨酸乙酯物理化学性质
[ 密度 ]:
1.2±0.1 g/cm3
[ 沸点 ]:
234.4±13.0 °C at 760 mmHg
[ 熔点 ]:
1 °C(lit.)
[ 分子式 ]:
C9H10O3
[ 分子量 ]:
166.174
[ 闪点 ]:
107.2±0.0 °C
[ 精确质量 ]:
166.062988
[ PSA ]:
46.53000
[ LogP ]:
2.77
[ 外观性状 ]:
透明液体
[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C
[ 折射率 ]:
1.539
[ 储存条件 ]:
包装完整、轻装轻卸,库房通风、远离明火、高温、与氧化剂分开存放
[ 水溶解性 ]:
slightly soluble
水杨酸乙酯MSDS
水杨酸乙酯毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- VO3000000
- CHEMICAL NAME :
- Salicylic acid, ethyl ester
- CAS REGISTRY NUMBER :
- 118-61-6
- BEILSTEIN REFERENCE NO. :
- 0907659
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 7
- MOLECULAR FORMULA :
- C9-H10-O3
- MOLECULAR WEIGHT :
- 166.19
- WISWESSER LINE NOTATION :
- QR BVO2
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 16,751,1978 ** ACUTE TOXICITY DATA **
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1320 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 16,751,1978
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - guinea pig
- DOSE/DURATION :
- 1400 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 16,751,1978
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - guinea pig
- DOSE/DURATION :
- 1500 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- AJPHAP American Journal of Physiology. (American Physiological Soc., 9650 Rockville Pike, Bethesda, MD 20814) V.1- 1898- Volume(issue)/page/year: 13,331,1905 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83194 No. of Facilities: 21 (estimated) No. of Industries: 1 No. of Occupations: 19 No. of Employees: 1865 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83194 No. of Facilities: 1242 (estimated) No. of Industries: 12 No. of Occupations: 22 No. of Employees: 18187 (estimated) No. of Female Employees: 11103 (estimated)
水杨酸乙酯安全信息
[ 符号 ]:
GHS07
[ 信号词 ]:
Warning
[ 危害声明 ]:
H302-H315-H319-H412
[ 警示性声明 ]:
P273-P301 + P312 + P330-P305 + P351 + P338
[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ 危害码 (欧洲) ]:
Xi:Irritant;
[ 风险声明 (欧洲) ]:
R22;R36/38
[ 安全声明 (欧洲) ]:
S26-S36
[ 危险品运输编码 ]:
NONH for all modes of transport
[ WGK德国 ]:
1
[ RTECS号 ]:
VO3000000
[ 海关编码 ]:
29182390
水杨酸乙酯合成路线
水杨酸乙酯上下游产品
水杨酸乙酯上游产品
水杨酸乙酯下游产品
水杨酸乙酯制备
由邻羟基苯甲酸(即水杨酸)与乙醇酯化而得。
水杨酸乙酯海关
[ 海关编码 ]: 2918230000
[ 中文概述 ]:
2918230000 水杨酸其他酯. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%
[ 申报要素 ]: 品名, 成分含量, 用途
[ Summary ]:
2918230000 other esters of salicylic acid and their salts VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%
水杨酸乙酯文献
J. Chromatogr. A. 1392 , 82-90, (2015)
Low thermal mass gas chromatography (LTM-GC) was evaluated for rapid, high peak capacity separations with three injection methods: liquid, headspace solid phase micro-extraction (HS-SPME), and direct ...
Occurrence and spatial distribution of EDCs and related compounds in waters and sediments of Iberian rivers.Sci. Total Environ. 503-504 , 69-86, (2015)
The environmental presence of chemicals capable of affecting the endocrine system has become a matter of scientific and public concern after certain endocrine disruptor compounds (EDCs) have been dete...
Analysis of endocrine disrupters and related compounds in sediments and sewage sludge using on-line turbulent flow chromatography-liquid chromatography-tandem mass spectrometry.J. Chromatogr. A. 1352 , 29-37, (2014)
A novel fully automated method based on dual column switching using turbulent flow chromatography followed by liquid chromatography coupled to tandem mass spectrometry (TFC-LC-MS/MS) was applied for t...
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相关化合物
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