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(R)-环氧丙烷

(R)-环氧丙烷用途

【用途一】
手性药物合成。

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(R)-环氧丙烷名称

[ CAS 号 ]:
15448-47-2

[ 中文名 ]:
(R)-(+)-环氧丙烷

[ 英文名 ]:
(R)-(+)-Propylene oxide

[中文别名 ]:

[英文别名 ]:

MFCD00066211
methyloxirane
propylene oxide
propene oxide
R-methyloxirane
UNII-Y4Y7NYD4BK
(R)-(+)-Propylene oxide
Propylene oxide, (R)-(+)-
(+)-methyloxirane
(R)-epoxypropane

(R)-环氧丙烷物理化学性质

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
32.9±8.0 °C at 760 mmHg

[ 分子式 ]:
C₃H₆O

[ 分子量 ]:
58.079

[ 闪点 ]:
-37.2±0.0 °C

[ 精确质量 ]:
58.041866

[ PSA ]:
12.53000

[ LogP ]:
0.13

[ 外观性状 ]:
无色至淡黄色液体

[ 蒸汽压 ]:
572.5±0.1 mmHg at 25°C

[ 折射率 ]:
1.399

[ 储存条件 ]:
0-10°C;存放于惰性气体之中;避免空气

[ 水溶解性 ]:
水溶性：可溶；水溶解度：405 g/l 20 °C

(R)-环氧丙烷MSDS

(R)-环氧丙烷毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: UJ2650000

CHEMICAL NAME :: Propylene oxide, (R)-(+)-

CAS REGISTRY NUMBER :: 15448-47-2

LAST UPDATED :: 199509

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C3-H6-O

MOLECULAR WEIGHT :: 58.09

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :: Sister chromatid exchange

TEST SYSTEM :: Rodent - hamster Lung

DOSE/DURATION :: 5 mmol/L

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 278,289,1992

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(R)-环氧丙烷安全信息

[ 符号 ]:

GHS02, GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H224-H301

[ 警示性声明 ]:
P210-P301 + P310

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US)

[ 危害码 (欧洲) ]:
F+:Highlyflammable;T:Toxic;

[ 风险声明 (欧洲) ]:
R12;R25

[ 安全声明 (欧洲) ]:
S45

[ 危险品运输编码 ]:
UN 1280

[ WGK德国 ]:
3

[ RTECS号 ]:
UJ2650000

[ 包装等级 ]:
I

[ 海关编码 ]:
2910900090

(R)-环氧丙烷合成路线

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(R)-环氧丙烷海关

[ 海关编码 ]: 2910900090

[ 中文概述 ]:
2910900090. 三节环环氧化物，环氧醇（酚，醚），包括其卤化，磺化，硝化或亚硝化的衍生物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2910900090. epoxides, epoxyalcohols, epoxyphenols and epoxyethers, with a three-membered ring, and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

(R)-环氧丙烷文献

The metal centers of particulate methane monooxygenase from Methylosinus trichosporium OB3b.

Biochemistry 47(26) , 6793-801, (2008)

Particulate methane monooxygenase (pMMO) is a membrane-bound metalloenzyme that oxidizes methane to methanol in methanotrophic bacteria. The nature of the pMMO active site and the overall metal conten...

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