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硫氰酸氯甲酯

硫氰酸氯甲酯名称

[ CAS 号 ]:
3268-79-9

[ 中文名 ]:
硫氰酸氯甲酯

[ 英文名 ]:
Thiocyanic acid,chloromethyl ester (7CI,8CI,9CI)

[中文别名 ]:

硫氰酸氯甲基

[英文别名 ]:

Chloromethylthiocyanate
chloro-thiocyanato-methane
Thiocyanic acid,chloromethyl ester
Chlormethylrhodanid
Chlor-methylthiocyanat
Chloromethylthiocyanogen
Chloromethyl thiocyanate
MFCD00001831
1-chloromethyl thiocyanate
EINECS 221-883-0

硫氰酸氯甲酯物理化学性质

[ 密度 ]:
1.37 g/mL at 25 °C(lit.)

[ 沸点 ]:
76-78 °C15 mm Hg(lit.)

[ 分子式 ]:
C₂H₂ClNS

[ 分子量 ]:
107.56200

[ 闪点 ]:
183 °F

[ 精确质量 ]:
106.96000

[ PSA ]:
49.09000

[ LogP ]:
1.39698

[ 折射率 ]:
n20/D 1.515(lit.)

硫氰酸氯甲酯MSDS

详细MSDS(安全技术说明书)

硫氰酸氯甲酯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: XK8800000

CHEMICAL NAME :: Thiocyanic acid, chloromethyl ester

CAS REGISTRY NUMBER :: 3268-79-9

BEILSTEIN REFERENCE NO. :: 1098487

LAST UPDATED :: 199612

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C2-H2-Cl-N-S

MOLECULAR WEIGHT :: 107.56

WISWESSER LINE NOTATION :: NCS1G

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 9572 ug/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PCBPBS Pesticide Biochemistry and Physiology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1971- Volume(issue)/page/year: 2,95,1972

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 5600 ug/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#03775

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硫氰酸氯甲酯安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302 + H312 + H332

[ 补充危害声明 ]:
Contact with acids liberates very toxic gas.

[ 警示性声明 ]:
P280

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R20/21/22;R32

[ 安全声明 (欧洲) ]:
S13-S36/37

[ 危险品运输编码 ]:
UN 2810 6.1/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
XK8800000

[ 包装等级 ]:
III

[ 危险类别 ]:
8

[ 海关编码 ]:
2930909090

硫氰酸氯甲酯合成路线

详细合成路线

硫氰酸氯甲酯上下游产品

硫氰酸氯甲酯上游产品

硫氰酸氯甲酯下游产品

硫氰酸氯甲酯海关

[ 海关编码 ]: 2930909090

[ 中文概述 ]:
2930909090. 其他有机硫化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

硫氰酸氯甲酯文献

Thiocyanate functionalised ionic liquids: synthesis, characterisation and reactivity. Zhao D, et al.

Eur. J. Inorg. Chem. 2007(2) , 279-284, (2007)

更多文献