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2-羟基-2-苯基乙酰胺

2-羟基-2-苯基乙酰胺名称

[ CAS 号 ]:
4410-31-5

[ 中文名 ]:
(±)-扁桃酰胺

[ 英文名 ]:
(+/-)-Mandelamide

[中文别名 ]:

[英文别名 ]:

MANDELAMIDE
2-Hydroxy-2-phenylacetamid
MFCD00025495
2-HYDROXY-2-PHENYLACETAMIDE
2-Phenyl-2-hydroxyacetamide
hydroxyphenylacetamide

2-羟基-2-苯基乙酰胺物理化学性质

[ 密度 ]:
1.246 g/cm3

[ 沸点 ]:
345.5ºC at 760 mmHg

[ 熔点 ]:
133-137ºC(lit.)

[ 分子式 ]:
C₈H₉NO₂

[ 分子量 ]:
151.16300

[ 闪点 ]:
162.7ºC

[ 精确质量 ]:
151.06300

[ PSA ]:
63.32000

[ LogP ]:
0.90560

[ 外观性状 ]:
白色结晶粉末

[ 储存条件 ]:
存放于惰性气体之中;避免空气

2-羟基-2-苯基乙酰胺安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302-H315-H319

[ 警示性声明 ]:
P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xn: Harmful;

[ 风险声明 (欧洲) ]:
22-36/37/38

[ 安全声明 (欧洲) ]:
26-36

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

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2-羟基-2-苯基乙酰胺文献

The mandelamide keto-enol system in aqueous solution. Generation of the enol by hydration of phenylcarbamoylcarbene.

J. Am. Chem. Soc. 125(1) , 187-94, (2003)

Flash photolysis of diazophenylacetamide in aqueous solution produced phenylcarbamoylcarbene, whose hydration generated a transient species that was identified as the enol isomer of mandelamide. This ...

[Molecular biology aspects of the antimicrobial effect of synthetic chemotherapeutic agents].

Z. Arztl. Fortbild. (Jena.) 76(15) , 662-6, (1982)

Catalytic asymmetric addition of dimethylzinc to alpha-ketoesters, using mandelamides as ligands.

Org. Lett. 8(7) , 1287-90, (2006)

[reaction: see text] A strategy based on the control of the electron-donating capabilities of the coordinating groups of the ligand has been applied in the catalytic asymmetric addition of organometal...

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