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苄氧基溴

苄氧基溴名称

[ CAS 号 ]:
618-32-6

[ 中文名 ]:
苯甲酰溴

[ 英文名 ]:
Benzoyl bromide

[中文别名 ]:

[英文别名 ]:

EINECS 210-544-2
MFCD00000112
benzoyl bromide

苄氧基溴物理化学性质

[ 密度 ]:
1.57 g/mL at 25 °C(lit.)

[ 沸点 ]:
218-219 °C(lit.)

[ 熔点 ]:
-24 °C

[ 分子式 ]:
C₇H₅BrO

[ 分子量 ]:
185.01800

[ 闪点 ]:
90 °C

[ 精确质量 ]:
183.95200

[ PSA ]:
17.07000

[ LogP ]:
2.22170

[ 外观性状 ]:
透明液体

[ 折射率 ]:
n20/D 1.589(lit.)

[ 储存条件 ]:
存放于惰性气体之中;避免光,湿气 (分解)

苄氧基溴MSDS

苄氧基溴安全信息

[ 符号 ]:

GHS05, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H314-H335

[ 补充危害声明 ]:
Reacts violently with water.

[ 警示性声明 ]:
P261-P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
C

[ 风险声明 (欧洲) ]:
R34

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45

[ 危险品运输编码 ]:
UN 3265 8/PG 2

[ WGK德国 ]:
3

[ 包装等级 ]:
II

[ 危险类别 ]:
8

[ 海关编码 ]:
2916399090

苄氧基溴合成路线

苄氧基溴上下游产品

苄氧基溴上游产品

苄氧基溴下游产品

苄氧基溴海关

[ 海关编码 ]: 2916399090

[ 中文概述 ]:
2916399090 其他芳香一元羧酸. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙烯酸、丙烯酸盐或酯应报明包装

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

苄氧基溴文献

Solvolysis of benzoyl halides in water/NH4DEHP/isooctane microemulsions.

Langmuir 22(18) , 7499-506, (2006)

A study was carried out on the solvolysis reactions of different benzoyl halides in microemulsions of water/NH4DEHP/isooctane, where NH4DEHP is ammonium bis(2-ethylhexyl) phosphate. Because of the low...

Zinc triflate-benzoyl bromide: a versatile reagent for the conversion of ether into benzoate protecting groups and ether glycosides into glycosyl bromides.

Carbohydr. Res. 338(5) , 447-9, (2003)

A simple and efficient method is developed for the chemoselective one-pot conversion of ethers (benzyl, TBDMS and acetal) to the corresponding benzoates by zinc triflate-catalyzed deprotection and ben...

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