溴代硝基甲烷结构式
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常用名 | 溴代硝基甲烷 | 英文名 | Bromonitromethane |
|---|---|---|---|---|
| CAS号 | 563-70-2 | 分子量 | 139.93600 | |
| 密度 | 2.07 | 沸点 | 146-148 °C (750 mmHg) | |
| 分子式 | CH2BrNO2 | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 4°C | |
| 符号 |
GHS03, GHS07 |
信号词 | Danger |
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Silyl imine electrophiles in enantioselective catalysis: a Rosetta Stone for peptide homologation, enabling diverse N-protected aryl glycines from aldehydes in three steps.
Org. Lett. , (2014) We report that N-(trimethylsilyl)imines serve in the Bis(AMidine)-catalyzed addition of bromonitromethane with a high degree of enantioselection. This allows for the production of a range of protected α-bromo nitroalkane donors (including Fmoc) for use in Ump... |
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Stereoselective synthesis of highly functionalized nitrocyclopropanes through the organocatalyic Michael-addition-initiated cyclization of bromonitromethane and β,γ-unsaturated α-ketoesters.
Chem. Asian J. 8(11) , 2859-63, (2013) A highly diastereo- and enantioselective cyclopropanation of β,γ-unsaturated α-ketoesters with bromonitromethane has been successfully developed through a domino Michael-addition/intramolecular-alkylation strategy. Acceptable yields (up to 89%) and enantiosel... |
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Synthesis of enantiopure 2-C-glycosyl-3-nitrochromenes.
J. Org. Chem. 78(24) , 12831-6, (2013) A novel methodology has been developed to obtain enantiopure 2-C-glycosyl-3-nitrochromenes. First, (Z)-1-bromo-1-nitroalkenes were prepared from the corresponding sugar aldehydes through a sodium iodide-catalyzed Henry reaction with bromonitromethane followed... |