2,2,2-三氯乙基氨基磺酸酯结构式
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常用名 | 2,2,2-三氯乙基氨基磺酸酯 | 英文名 | 2,2,2-Trichloroethoxysulfonamide |
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CAS号 | 69226-51-3 | 分子量 | 228.48200 | |
密度 | 1.801g/cm3 | 沸点 | 288.7ºC at 760 mmHg | |
分子式 | C2H4Cl3NO3S | 熔点 | 56 °C | |
MSDS | 中文版 美版 | 闪点 | 128.4ºC |
Catalytic intermolecular amination of C-H bonds: method development and mechanistic insights.
J. Am. Chem. Soc. 129 , 562, (2007) Reaction methodology for intermolecular C-H amination of benzylic and 3 degrees C-H bonds is described. This process uses the starting alkane as the limiting reagent, gives optically pure tetrasubstituted amines through stereospecific insertion into enantiome... |