3-丁烯腈
一般危化品
3-丁烯腈结构式
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常用名 | 3-丁烯腈 | 英文名 | 3-Butenenitrile |
|---|---|---|---|---|
| CAS号 | 109-75-1 | 分子量 | 67.089 | |
| 密度 | 0.834 | 沸点 | 116-121 ºC | |
| 分子式 | C4H5N | 熔点 | -87°C | |
| MSDS | 中文版 美版 | 闪点 | 23.9±0.0 °C | |
| 符号 |
GHS02, GHS06 |
信号词 | Danger |
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In vitro metabolic conversion of the organic breakdown products of glucosinolate to goitrogenic thiocyanate anion.
J. Sci. Food Agric. 95 , 2244-51, (2015) Glucosinolates are abundant in Brassicaceae vegetables, and they are degraded into various organic breakdown products (BPs) (R-CN, -NCS and -SCN) by myrosinase when plant tissues are damaged. This study was designed to investigate whether these BPs could be b... |
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Comparative developmental toxicities of aliphatic nitriles: in vivo and in vitro observations.
Toxicol. Appl. Pharmacol. 163(2) , 149-63, (2000) The effects on embryonic development of a series of eight saturated (acetonitrile, propionitrile, and n-butyronitrile) and unsaturated (acrylonitrile, methacrylonitrile, allylnitrile, cis-2-pentenenitrile, and 2-chloroacrylonitrile) nitriles were compared in ... |
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A new unifying hypothesis for lathyrism, konzo and tropical ataxic neuropathy: nitriles are the causative agents.
Food Chem. Toxicol. 49(3) , 563-70, (2011) Konzo and lathyrism are associated with consumption of cassava and grass pea, respectively. Cassava consumption has also been associated with a third disease, tropical ataxic neuropathy (TAN). This review presents a new unifying hypothesis on the causative ag... |
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Direct catalytic asymmetric addition of allylic cyanides to aldehydes for expeditious access to enantioenriched unsaturated δ-valerolactones.
Chem. Asian J. 8(2) , 354-8, (2013)
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Synthesis and application of modular phosphine-phosphoramidite ligands in asymmetric hydroformylation: structure-selectivity relationship.
Chemistry 16(3) , 871-7, (2010) A series of hybrid phosphine-phosphoramidite ligands has been designed and synthesized in moderate yields from chiral BINOL (1,1'-bi-2-naphthol) or NOBIN (2-amino-2'-hydroxy-1,1'-binaphthyl). They have achieved highly regio- and enantioselectivities in Rh-cat... |
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The Brassica epithionitrile 1-cyano-2,3-epithiopropane triggers cell death in human liver cancer cells in vitro.
Mol. Nutr. Food. Res. 59 , 2178-89, (2016) Glucosinolates are secondary metabolites present in Brassica vegetables. Alkenyl glucosinolates are enzymatically degraded forming nitriles or isothiocyanates, but in the presence of epithiospecifier protein, epithionitriles are released. However, studies on ... |
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Stability of glucosinolates and glucosinolate degradation products during storage of boiled white cabbage.
Food Chem. 203 , 340-7, (2016) The aim of the study was to investigate the effect of storage on the contents of glucosinolates (GLS) and their degradation products in a boiled white cabbage. A 24h storage at 4 °C resulted in a decrease in GLS content (20-40%, depending on the cooking time ... |
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Glucosinolate breakdown products as insect fumigants and their effect on carbon dioxide emission of insects.
BMC Ecol. 2 , 5, (2004) Glucosinolate breakdown products are volatile, therefore good candidates for insect fumigants. However, although they are insecticidal, the mode of action of such natural products is not clear. We studied the insecticidal effect of these compounds as fumigant... |
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Verticillium suppression is associated with the glucosinolate composition of Arabidopsis thaliana leaves.
PLoS ONE 8 , e71877, (2013) The soil-borne fungal pathogen Verticillium longisporum is able to penetrate the root of a number of plant species and spread systemically via the xylem. Fumigation of Verticillium contaminated soil with Brassica green manure is used as an environmentally fri... |
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Direct catalytic asymmetric addition of allyl cyanide to ketones via soft Lewis acid/hard Brønsted base/hard Lewis base catalysis.
J. Am. Chem. Soc. 132(15) , 5522-31, (2010) We report that a hard Lewis base substantially affects the reaction efficiency of direct catalytic asymmetric gamma-addition of allyl cyanide (1a) to ketones promoted by a soft Lewis acid/hard Brønsted base catalyst. Mechanistic studies have revealed that Cu/... |