亚膦酸三(1,1,1,3,3,3-六氟-2-丙基)酯
亚膦酸三(1,1,1,3,3,3-六氟-2-丙基)酯结构式
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常用名 | 亚膦酸三(1,1,1,3,3,3-六氟-2-丙基)酯 | 英文名 | tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite |
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| CAS号 | 66470-81-3 | 分子量 | 532.06300 | |
| 密度 | 1.69 g/mL at 25ºC(lit.) | 沸点 | 130ºC(lit.) | |
| 分子式 | C9H3F18O3P | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 44.5ºC | |
| 符号 |
GHS07 |
信号词 | Warning |
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Solid phase synthesis of oligoribonucleotides using the 1-[(2-chloro-4-methyl)phenyl]-4-methoxypiperidin-4-yl (Ctmp) group for the protection of the 2'-hydroxy functions and the H-phosphonate approach.
Nucleic Acids Res. 17(10) , 3689-97, (1989) The solid phase synthesis of oligoribonucleotides using the H-phosphonate approach and the 1-[(2-chloro-4-methyl)phenyl]-4-methoxypiperidin-4-yl (Ctmp) and dimethoxytrityl (DMTr) groups, respectively, for the protection of the 2'- and 5'-hydroxy functions is ... |
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Use of new phosphonylating and coupling agents in the synthesis of oligodeoxyribonucleotides via the H-phosphonate approach.
Nucleic Acids Res. 18(11) , 3327-31, (1990) New phosphonylating and coupling agents for the synthesis of oligodeoxyribonucleotides via H-phosphonate approach have been developed. Tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite, prepared by the reaction of lithium salt of 1,1,1,3,3,3-hexafluoro-2-propox... |
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Stereoselective propargylation mediated by a chiral metal cluster: reactions of [(propargylium)Co2 (CO)5{P(OR)3}][BF4] with carbon nucleophiles. Caffyn AJM and Nicholas KM.
J. Am. Chem. Soc. 115(14) , 6438-6439, (1993)
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Synthesis of antisense oligodeoxyribonucleotide analogues by use of deoxyribonucleoside 3'-bis(1,1, 1,3,3,3-hexafluoro-2-propyl)phosphites as new key intermediates. Hosaka H, et al.
Heteroatom Chem. 2(1) , 197-204, (1991)
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Preparation and nuclear magnetic resonance studies of pentacoordinated phosphorus compounds containing hexafluoroisopropoxy groups. Denney DB, et al.
J. Org. Chem. 48(13) , 2159-2164, (1983)
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