甲基三氯硅烷结构式
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常用名 | 甲基三氯硅烷 | 英文名 | Methyltrichlorosilane |
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CAS号 | 75-79-6 | 分子量 | 149.479 | |
密度 | 1.3±0.1 g/cm3 | 沸点 | 73.5±3.0 °C at 760 mmHg | |
分子式 | CH3Cl3Si | 熔点 | -77 °C | |
MSDS | 中文版 美版 | 闪点 | -15.0±0.0 °C | |
符号 |
GHS02, GHS05, GHS06 |
信号词 | Danger |
Enzyme electrode for the measurement of lactate in undiluted blood.
Clin. Chim. Acta 157(2) , 191-8, (1986) An enzyme electrode is described based upon the enzyme lactate oxidase (EC 1.1.3.2) coupled to an H2O2 sensor. Use of an organosilane-treated microporous membrane over the enzyme layer, allows responses linear to 18 mmol/l L-lactate with response times of 1-3... |
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Theoretical study of the pyrolysis of methyltrichlorosilane in the gas phase. 3. Reaction rate constant calculations.
J. Phys. Chem. A 114(6) , 2384-92, (2010) The rate constants for the gas-phase reactions in the silicon carbide chemical vapor deposition of methyltrichlorosilane (Ge, Y. B.; Gordon, M. S.; Battaglia, F.; Fox, R. O. J. Phys. Chem. A 2007, 111, 1462.) were calculated. Transition state theory was appli... |
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Theoretical study of the pyrolysis of methyltrichlorosilane in the gas phase. 2. Reaction paths and transition states.
J. Phys. Chem. A 111(8) , 1475-86, (2007) The kinetics for the previously proposed 114-reaction mechanism for the chemical vapor deposition (CVD) process that leads from methyltrichlorosilane (MTS) to silicon carbide (SiC) are examined. Among the 114 reactions, 41 are predicted to proceed with no int... |
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Preparation of highly hydrophobic and lipophobic cellulose fibers by a straightforward gas-solid reaction.
J. Colloid. Interface Sci. 344(2) , 588-95, (2010) This work describes a very simple, rapid, and efficient approach to the hydrophobization and lipophobization of cellulose fibers through their reaction with gaseous trichloromethylsilane (TCMS). The characterization of the modified surface involved FTIR-ATR a... |
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Theoretical study of the pyrolysis of methyltrichlorosilane in the gas phase. 1. Thermodynamics.
J. Phys. Chem. A 111(8) , 1462-74, (2007) Structures and energies of the gas-phase species produced during and after the various unimolecular decomposition reactions of methyltrichlorosilane (MTS) with the presence of H2 carrier gas were determined using second-order perturbation theory (MP2). Single... |
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Synthesis of silicon carbide nanotubes by chemical vapor deposition.
J. Nanosci. Nanotechnol. 7(2) , 647-52, (2007) Silicon carbide nanotubes (SiCNTs) were directly synthesized by chemical vapor deposition (CVD) in the paper. Methyltrichlorosilane (MTS) was selected as the SiC gaseous source and, ferrocence and thiophene as the catalyst and the cocatalyst, respectively. Th... |
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Disulfide bond rearrangement during regioselective oxidation in PhS(O)Ph/CH3SiCl3 mixture for the synthesis of alpha-conotoxin GI.
Biopolymers 88(1) , 20-8, (2007) Rearrangement of disulfide bonds during the synthesis of alpha-conotoxin GI using PhS(O)Ph/CH(3)SiCl(3) oxidation procedure was observed. We have demonstrated that the protecting scheme (order of acetamidomethyl (Acm) and (t)Bu protecting groups) of the Cys r... |
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[A novel synthetic approach of tryptophan-containing cystine peptides by regioselective disulfide bond-forming reaction using the silyl chloride-sulfoxide system].
Yakugaku Zasshi 120(2) , 197-205, (2000) A general scheme for the efficient synthesis of Trp-containing cystine peptide by the successive treatment with methyltrichlorosilane-diphenylsulfoxide in trifluoroacetic acid (TFA) and trifluoromethanesulfonic acid (TFMSA)-thioanisole in TFA, is described. A... |
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Facile Preparation of Nanostructured, Superhydrophobic Filter Paper for Efficient Water/Oil Separation.
PLoS ONE 11 , e0151439, (2016) In this paper, we present a facile and cost-effective method to obtain superhydrophobic filter paper and demonstrate its application for efficient water/oil separation. By coupling structurally distinct organosilane precursors (e.g., octadecyltrichlorosilane ... |