降冰片烯
降冰片烯结构式
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常用名 | 降冰片烯 | 英文名 | NORBORNENE |
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| CAS号 | 498-66-8 | 分子量 | 94.154 | |
| 密度 | 1.0±0.1 g/cm3 | 沸点 | 96.0±0.0 °C at 760 mmHg | |
| 分子式 | C7H10 | 熔点 | 44-46 °C(lit.) | |
| MSDS | 美版 | 闪点 | -15.0±0.0 °C | |
| 符号 |
GHS02, GHS07, GHS09 |
信号词 | Danger |
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Self-activation in de novo designed mimics of cell-penetrating peptides.
Angew. Chem. Int. Ed. Engl. 50 , 6147, (2011)
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[Establishment of the maximum permissible concentrations of norbornene, norbornadiene and dicyclopentadiene in reservoir water].
Gig. Sanit. (2) , 77-9, (1986)
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Pd(II)-catalyzed regioselective 2-alkylation of indoles via a norbornene-mediated C-H activation: mechanism and applications.
J. Am. Chem. Soc. 134(35) , 14563-72, (2012) A palladium-catalyzed direct 2-alkylation reaction of free N-H indoles was developed based on a norbornene-mediated regioselective cascade C-H activation. The detailed reaction mechanism was investigated by NMR spectroscopic analyses, characterization of the ... |
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A genetically encoded norbornene amino acid for the mild and selective modification of proteins in a copper-free click reaction.
Angew. Chem. Int. Ed. Engl. 51(18) , 4466-9, (2012)
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Evaluation of norbornene- beta-cyclodextrin-based monomers and oligomers as chiral selectors by means of nonaqueous capillary electrophoresis.
Electrophoresis 22(1) , 109-16, (2001) Norbornen-5-yl carboxylic acid and norbornen-5-ylmethylsilyl ether-based beta-cyclodextrins (beta-CDs) containing up to three norbornene ester and up to five norbornene silyl ether units have been prepared from beta-CD and norbornen-5-carboxylic chloride and ... |
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Bis-exo-2-norbornylboron triflate for stereospecific enolization of 3,3,3-trifluoropropionates.
Org. Lett. 12(20) , 4474-7, (2010) The first boron-mediated enolization-aldolization of 3,3,3-trifluoropropionates has been reported. The preparation and application of bis-exo-bicyclo[2.2.1]heptan-2-ylboron triflate as a superior reagent for diastereospecific enolization has also been describ... |
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Room temperature asymmetric Pd-catalyzed methoxycarbonylation of norbornene: highly selective catalysis and HP-NMR studies.
Dalton Trans. 41(23) , 6980-91, (2012) Palladium complexes bearing monodentate and bidentate phosphine ligands (1-7) were synthesised and used as catalyst precursors in the methoxycarbonylation of norbornene. The catalytic systems bearing ligands 1, 3 and 4 afforded excellent conversions (>99%) an... |
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Oligomers of cis-beta-norbornene amino acid: formation of beta-strand mimetics.
Chem. Commun. (Camb.) (14) , 1548-50, (2006) The oligomers of constrained cis-exo-beta-norbornene amino acid were synthesised and characterised by extensive NMR, CD, IR and MD studies. The results showed the formation of both right and left handed consecutive 6-membered hydrogen-bonded strands for [2S,3... |
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Effect of structure of the redox molecular sieve TS-1 on the oxidation of phenol, crotyl alcohol and norbornylene.
Phys. Chem. Chem. Phys. 7(13) , 2671-8, (2005) A range of crystalline TS-1 samples with different morphologies as well as the corresponding TS-1 precursor structures have been synthesised using hydrothermal crystallisation. The materials have been characterised using powder X-ray diffraction, IR and Raman... |
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Synthesis of classical prostaglandins.
Adv. Prostaglandin. Thromboxane. Leukot. Res. 14 , 73-129, (1985)
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