叔丁基磷酸
叔丁基磷酸结构式
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常用名 | 叔丁基磷酸 | 英文名 | dioxido-oxo-tert-butyl-phosphorane |
|---|---|---|---|---|
| CAS号 | 4923-84-6 | 分子量 | 138.10200 | |
| 密度 | 1.083 (estimate) | 沸点 | 255.4ºC at 760 mmHg | |
| 分子式 | C4H11O3P | 熔点 | 187-189ºC(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 108.3ºC | |
| 符号 |
GHS05 |
信号词 | Danger |
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Borophosphonate cages: easily accessible and constitutionally dynamic heterocubane scaffolds.
Chemistry 18(32) , 9939-45, (2012) A versatile and experimentally facile procedure for the synthesis of borophosphonate cages of the general formula [tBuPO(3)BR'](4) is described. The method involves heating of tert-butylphosphonic acid with a boronic acid in toluene to give borophosphonates i... |
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Hexanuclear copper(II) cages built on a central {μ3-O···H···μ3-O} moiety, 1,3-bis(dimethylamino)-2-propanolato and capping R-phosphonates: crystal structures, magnetic behavior, and DFT studies.
Inorg. Chem. 51(12) , 6842-50, (2012) The syntheses, structural characterization, and magnetic behavior of two new hexanuclear copper(II) complexes derived from R-phosphonic acids and 1,3-bis(dimethylamino)-2-propanol (Hbdmap) with formulas [Cu(6)(μ-bdmap)(3)(μ(3)-Ph-PO(3))(2)(μ(3)-O···H···μ(3)-O... |
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Multicomponent assembly of anionic and neutral decanuclear copper(II) phosphonate cages.
Inorg. Chem. 51(10) , 5605-16, (2012) A multicomponent synthetic strategy involving copper(II) ions, tert-butylphosphonic acid (t-BuPO(3)H(2)) and 3-substituted pyrazole ligands has been adopted for the synthesis of soluble molecular copper(II) phosphonates. The use of six different 3-substituted... |
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Di-, tri- and tetranuclear molecular vanadium phosphonates: a chloride encapsulated tetranuclear bowl.
Dalton Trans. 43(28) , 10898-909, (2014) The reaction of vanadium(III) trichloride with tert-butylphosphonic acid (t-BuPO3H2) in the presence of 1,10-phenanthroline/2,2'-bipyridine as an ancillary ligand in acetonitrile at room temperature afforded two dinuclear dicationic vanadium(IV) complexes [(V... |
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Highly selective luminescent nanostructures for mitochondrial imaging and targeting.
Nanoscale 8 , 3350-61, (2016) Here a luminescent hybrid nanostructure based on functionalized quantum dots (QDs) is used as a fluorescent imaging agent able to target selectively mitochondria thanks to the molecular recognition of the translocator protein (TSPO). The selective targeting o... |