三氯氧磷
一般危化品
三氯氧磷结构式
|
常用名 | 三氯氧磷 | 英文名 | phosphoryl trichloride |
|---|---|---|---|---|
| CAS号 | 10025-87-3 | 分子量 | 153.332 | |
| 密度 | 1.8±0.1 g/cm3 | 沸点 | 105.3±9.0 °C at 760 mmHg | |
| 分子式 | Cl3OP | 熔点 | 1.25 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 105.8°C | |
| 符号 |
GHS05, GHS06, GHS08 |
信号词 | Danger |
|
Design of donor-acceptor star-shaped oligomers for efficient solution-processible organic photovoltaics.
Faraday Discuss. 174 , 313-39, (2014) This contribution describes recent progress in the design, synthesis and properties of solution-processible star-shaped oligomers and their application in organic photovoltaics. Even though alternative chemistry has been used to design such oligomers, the mos... |
|
|
Toughened hydrogels inspired by aquatic caddisworm silk.
Soft Matter 11 , 6981-90, (2015) Aquatic caddisworm silk is a tough adhesive fiber. Part of the toughening mechanism resides in serial, Ca(2+)-phosphate crosslinked nano-domains that comprise H-fibroin, the major structural protein. To mimic the toughening mechanism, a synthetic phosphate-gr... |
|
|
Differentiation between acetylcholinesterase and the organophosphate-inhibited form using antibodies and the correlation of antibody recognition with reactivation mechanism and rate.
J. Biol. Chem. 278(46) , 45512-8, (2003) Two types of polyclonal antibodies were generated from (a) a decapeptide sequence that includes the active site serine of acetylcholinesterase (anti-AChE10S) and (b) the identical decapeptide sequence phosphorylated at the active site serine of acetylcholines... |
|
|
POCl3 chlorination of 4-quinazolones.
J. Org. Chem. 76(6) , 1653-61, (2011) The reaction of quinazolones with POCl(3) to form the corresponding chloroquinazolines occurs in two distinct stages, which can be separated through appropriate temperature control. An initial phosphorylation reaction occurs readily under basic conditions (R(... |
|
|
Facile small scale synthesis of nucleoside 5'-phosphate mixtures.
Nucleosides Nucleotides Nucleic Acids 29(1) , 14-26, (2010) We present a facile method to phosphorylate small amounts of nucleosides (0.05 mumol) into mixtures of their 5'-mono-, di-, and triphosphates in a one-pot reaction. The nucleosides were first converted into their dichlorophosphates using a large excess (15-18... |
|
|
Formation of the Vilsmeier-Haack complex: the performance of different levels of theory.
J. Mol. Model. 17(12) , 3209-17, (2011) Because of discrepancies in the available experimental data, an extensive theoretical investigation of the formation of the Vilsmeier-Haack (VH) complex has been carried out. The barriers to complex formation calculated using eight different density functiona... |
|
|
Electrospray ionization mass spectrometric studies of phosphorus oxychloride directed synthesis of homo-oligopeptide ester libraries.
Rapid Commun. Mass Spectrom. 16(10) , 919-22, (2002) With the assistance of phosphorus oxychloride, alpha-amino acids were assembled into homo-peptides, which were analyzed by electrospray ionization mass spectrometry (ESI-MS) and multistage electrospray ionization mass spectrometry (ESI-MS/MS). On quenching wi... |
|
|
Synthesis, characterization and evaluation of 1,2-bis(2,4,6-trinitrophenyl) hydrazine: a key precursor for the synthesis of high performance energetic materials.
J. Hazard. Mater. 172(1) , 276-9, (2009) 1,2-Bis(2,4,6-trinitrophenyl) hydrazine (3) is one of the precursors in the synthesis of an important energetic material viz., hexanitrazobenzene. The simple and convenient lab scale synthesis of title compound (3) was carried out by the condensation of picry... |
|
|
One pot conjugation of the polypeptides directed by phosphorus oxychloride.
J. Pept. Res. 65(4) , 427-32, (2005) A series of homopeptides and their conjugates were synthesized in one pot reaction in the presence of phosphorus oxychloride and the conjugate yield was structurally dependent. Menthol and benzylamine conjugated to the homopeptides quantitatively. Homopeptide... |
|
|
Hydrolysis studies of phosphodichloridate and thiophosphodichloridate ions.
J. Org. Chem. 77(13) , 5829-31, (2012) We report the pH-k(obs) profiles for the hydrolyses of phosphodichloridate and thiophosphodichloridate ions in aqueous solutions. Both species show broad pH-k(obs) plateaus that extend to high pHs. |