3-(二甲氨基)-5,5-二甲基-2-环己烯-1-酮
3-(二甲氨基)-5,5-二甲基-2-环己烯-1-酮结构式
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常用名 | 3-(二甲氨基)-5,5-二甲基-2-环己烯-1-酮 | 英文名 | 3-(DIMETHYLAMINO)-5,5-DIMETHYL-2-CYCLOHEXEN-1-ONE |
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| CAS号 | 31039-88-0 | 分子量 | 167.24800 | |
| 密度 | 0.96g/cm3 | 沸点 | 233ºC at 760mmHg | |
| 分子式 | C10H17NO | 熔点 | 95-96ºC(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 72.6ºC | |
| 符号 |
GHS07 |
信号词 | Warning |
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Photoactivation of amino-substituted 1,4-benzoquinones for release of carboxylate and phenolate leaving groups using visible light.
J. Org. Chem. 71(16) , 6053-60, (2006) Upon exposure to visible light, 2-pyrrolidino-substituted 3,6-dimethyl-1,4-benzoquinones photocyclize to give benzoxazolines with quantum yields of 0.07-0.10 in CH2Cl2, 0.02-0.04 in CH3CN, and <0.01 in 30% aq CH3CN. With carboxylate or phenolate leaving group... |
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