3-(DIMETHYLAMINO)-5,5-DIMETHYL-2-CYCLOHEXEN-1-ONE
3-(DIMETHYLAMINO)-5,5-DIMETHYL-2-CYCLOHEXEN-1-ONE structure
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Common Name | 3-(DIMETHYLAMINO)-5,5-DIMETHYL-2-CYCLOHEXEN-1-ONE | ||
|---|---|---|---|---|
| CAS Number | 31039-88-0 | Molecular Weight | 167.24800 | |
| Density | 0.96g/cm3 | Boiling Point | 233ºC at 760mmHg | |
| Molecular Formula | C10H17NO | Melting Point | 95-96ºC(lit.) | |
| MSDS | Chinese USA | Flash Point | 72.6ºC | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Photoactivation of amino-substituted 1,4-benzoquinones for release of carboxylate and phenolate leaving groups using visible light.
J. Org. Chem. 71(16) , 6053-60, (2006) Upon exposure to visible light, 2-pyrrolidino-substituted 3,6-dimethyl-1,4-benzoquinones photocyclize to give benzoxazolines with quantum yields of 0.07-0.10 in CH2Cl2, 0.02-0.04 in CH3CN, and <0.01 in 30% aq CH3CN. With carboxylate or phenolate leaving group... |
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