三苯基膦氯金
三苯基膦氯金结构式
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常用名 | 三苯基膦氯金 | 英文名 | Gold(1+) chloride-triphenylphosphine (1:1:1) |
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| CAS号 | 14243-64-2 | 分子量 | 494.71 | |
| 密度 | N/A | 沸点 | 360ºC at 760 mmHg | |
| 分子式 | C18H15AuClP | 熔点 | 248-249°C | |
| MSDS | 中文版 美版 | 闪点 | 181.7ºC | |
| 符号 |
GHS07 |
信号词 | Warning |
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A mass spectrometric investigation of the binding of gold antiarthritic agents and the metabolite [Au(CN)2]- to human serum albumin.
J. Biol. Inorg. Chem. 11(5) , 559-70, (2006) Electrospray ionisation (ESI) mass spectrometry was used to examine the reactions of the clinically used antiarthritic agent [Au(S2O3)2]3-, and AuPEt3Cl, a derivative of another clinically used agent auranofin, with human serum albumin (HSA) obtained from a h... |
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Development of a gold-multifaceted catalysis approach to the synthesis of highly substituted pyrroles: mechanistic insights via Huisgen cycloaddition studies.
J. Org. Chem. 78(3) , 920-34, (2013) A novel gold-catalyzed method for the regioselective synthesis of highly substituted pyrroles directly from oximes and alkynes was developed via independent optimization of two key steps of the process. Importantly, a cationic gold(I) species was shown to act... |
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A powerful chiral counterion strategy for asymmetric transition metal catalysis.
Science 317 , 496-499, (2007) Traditionally, transition metal-catalyzed enantioselective transformations rely on chiral ligands tightly bound to the metal to induce asymmetric product distributions. Here we report high enantioselectivities conferred by a chiral counterion in a metal-catal... |
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Au(I)-catalyzed cyclization of enynes bearing an olefinic cycle.
J. Org. Chem. 71 , 9366, (2006) Gold(I)-catalyzed cyclization of enynes containing an olefinic cycle has been studied. The introduction of an olefinic ring instead of a terminal alkene in enynes dramatically increased the yield of the reaction. Enynes having an olefinic cycle were prepared ... |
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Synthesis, structure and cytotoxicity of triphenylphosphinegold(I) sulfanylpropenoates.
J. Inorg. Biochem. 102(2) , 184-92, (2008) The reaction of triphenylphosphinegold(I) chloride in ethanol in a 1:1 molar ratio with the 3-(aryl)-2-sulfanylpropenoic acids H(2)xspa [x: p=3-phenyl-, Clp=3-(2-chlorophenyl)-, -o-mp=3-(2-methoxyphenyl)-, -p-mp=3-(4-methoxyphenyl)-, -o-hp=3-(2-hydroxyphenyl)... |
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Au(PPh(3))Cl-AgSbF(6)-catalyzed rearrangement of propargylic 1,3-dithianes: formation of 8-membered 1,3-bisthio-substituted cyclic allenes.
Chem. Commun. (Camb.) (18) , 2535-7, (2009) Au(PPh(3))Cl-AgSbF(6)-catalyzed rearrangement of propargylic 1,3-dithiane leads to the formation of 8-membered dithio-substituted cyclic allenes, which are remarkably stable. |
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Efficient synthesis of β-enaminones and β-enaminoesters catalyzed by gold (I)/silver (I) under solvent-free conditions.
Molecules 17(3) , 2812-22, (2012) An efficient method for the synthesis of β-enaminones and β-enaminoesters using a combination of [(PPh(3))AuCl]/AgOTf as catalyst has been developed. The reaction between 1,3-dicarbonyl compounds and primary amines was carried out under solvent-free condition... |
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Synlett , 3309, (2006)
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Leseurre, L. et al.
Org. Lett. 9 , (2007)
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