氯化钼(III)
一般危化品
氯化钼(III)结构式
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常用名 | 氯化钼(III) | 英文名 | Molybdenum(III) chloride |
|---|---|---|---|---|
| CAS号 | 13478-18-7 | 分子量 | 202.299 | |
| 密度 | 3.58 g/mL at 25 °C(lit.) | 沸点 | N/A | |
| 分子式 | Cl3Mo | 熔点 | 1027°C | |
| MSDS | 中文版 美版 | 闪点 | N/A | |
| 符号 |
GHS07 |
信号词 | Warning |
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Synthesis of highly functionalized 9,10-phenanthrenequinones by oxidative coupling using MoCl5.
Org. Lett. 14(12) , 2976-9, (2012) The strong oxidative power of molybdenum pentachloride gives rise to an efficient oxidative C-C bond formation of benzil derivatives to the corresponding 9,10-phenanthrenequinones. A highly complementary method to previous approaches was developed. The requir... |
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Genotoxic activities in vivo of cobaltous chloride and other metal chlorides as assayed in the Drosophila wing spot test.
Mutat. Res. 320(1-2) , 133-40, (1994) A series of metal chlorides were subjected to the wing spot test of Drosophila melanogaster. In the test, larvae trans-heterozygous for the wing-hair mutations mwh and flr were orally treated at the third instar stage with a test compound and the wings were i... |
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Novel domino oxidative coupling: C-C bond formation sequence to highly functionalized dibenzo[a,c]cycloheptenes.
Org. Lett. 13(5) , 916-9, (2011) A domino sequence involving various MoCl(5)-mediated oxidations followed by trapping and supposed [3,3]-sigmatropic rearrangement provides a fast access to the full carbon skeleton of metasequirin-B. A variety of different moieties R(1) and R(2) are tolerated... |
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Remarkably fast and selective aromatization of Hantzsch esters with MoOCl4and MoCl5: A chemical model for possible biologically relevant properties of molybdenum-containing enzymes
Bioorg. Med. Chem. Lett. 22(11) , 3676-81, (2012) Selective aromatization of Hantzsch esters with MoOCl4 or MoCl5 is described. The reaction employing MoOCl4 proceeds smoothly under reflux of acetonitrile within 1–20min and the products of high purity were isolated in good-to-excellent yields (70–99%). From ... |