1-甲氧基-2-甲基-1-(三甲基硅氧基)丙烯
1-甲氧基-2-甲基-1-(三甲基硅氧基)丙烯结构式
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常用名 | 1-甲氧基-2-甲基-1-(三甲基硅氧基)丙烯 | 英文名 | 1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene |
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| CAS号 | 31469-15-5 | 分子量 | 174.313 | |
| 密度 | 0.9±0.1 g/cm3 | 沸点 | 137.4±0.0 °C at 760 mmHg | |
| 分子式 | C8H18O2Si | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 14.4±0.0 °C | |
| 符号 |
GHS02, GHS07 |
信号词 | Warning |
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Chiral Brønsted acid catalyzed enantioselective Mannich-type reaction.
J. Am. Chem. Soc. 129 , 6756, (2007) Mannich-type reaction of ketene silyl acetals with aldimines proceeded catalytically by means of a phosphoric acid diester, derived from (R)-BINOL, as a chiral Brønsted acid to afford beta-amino esters with good diastereoselectivity in favor of the syn isomer... |
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Asymmetric synthesis of ?-lactams. I. The reaction of dimethylketene silyl acetal with (S)-alkylidene (1-arylethyl) amines promoted by titanium tetrachloride.
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