己酰氯
一般危化品
己酰氯结构式
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常用名 | 己酰氯 | 英文名 | Hexanoyl chloride TOP1 supplier |
|---|---|---|---|---|
| CAS号 | 142-61-0 | 分子量 | 134.604 | |
| 密度 | 1.0±0.1 g/cm3 | 沸点 | 152.2±3.0 °C at 760 mmHg | |
| 分子式 | C6H11ClO | 熔点 | -87°C | |
| MSDS | 中文版 美版 | 闪点 | 50.0±0.0 °C | |
| 符号 |
GHS02, GHS05 |
信号词 | Danger |
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Remarkably regioselective deacylation of cellulose esters using tetraalkylammonium salts of the strongly basic hydroxide ion.
Carbohydr. Polym. 111 , 25-32, (2014) Tetraalkylammonium hydroxides have been found to mediate regioselective deacylation of cellulose esters. This deacylation surprisingly shows substantial selectivity for the removal of the acyl groups at O-2/3, affording cellulose-6-O-esters by a simple, effic... |
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Use of multivariate statistical techniques to optimize the separation of 17 capsinoids by ultra performance liquid chromatography using different columns.
Talanta 134 , 256-63, (2015) In this work a multivariate statistical tool (Derringer and Suich optimization) was proposed for the separation of seventeen capsinoids (natural and synthetic) using the UHPLC-DAD chromatography. Capsinoids were analyzed at 280 nm. The variables optimized wer... |
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One-step dispersion of cellulose nanofibers by mechanochemical esterification in an organic solvent.
ChemSusChem 5(12) , 2319-22, (2012) Got a crush: Native cellulose can be dispersed as nanofibers in organic solvents by ball milling with esterification agents. Milling with hexanoyl chloride/DMF gives hexanoyl-coated nanofibers dispersible in several organic solvents. Milling with succinic anh... |
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An efficient total synthesis of ruprechstyril from Ruprechtia tangarana.
Nat. Prod. Res. 27(13) , 1153-8, (2013) A short total synthesis of natural isocarbostyril ruprechstyril (3-n-pentyl-6-methoxy-8-hydroxy-1(2H)-isoquinolinone) isolated from Ruprechtia tangarana is reported. 6,8-Dimethoxy-3-pentylisocoumarin obtained by condensation of 3,5-dimethoxyhomophthalic anhyd... |
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A facile asymmetric synthesis of (s)-14-methyl-1-octadecene, the sex pheromone of the peach leafminer moth.
Molecules 18(5) , 5201-8, (2013) An asymmetric synthesis of 14-methyl-1-octadecene, the sex pheromone of the peach leafminer moth has been achieved. The target molecule was synthesized in six linear steps and in 30.3% overall yield from commercially available hexanoyl chloride, (S)-4-benzylo... |
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Total synthesis and antibacterial screening of ( ± )-7-butyl-6,8-dihydroxy-3-pentyl-3,4-dihydroisochromen-1-one.
J. Asian Nat. Prod. Res. 15(10) , 1112-22, (2013) A new total synthesis of ( ± )-7-butyl-6,8-dihydroxy-3-pentyl-3,4-dihydroisochromen-1-one, isolated as R-enantiomer from Geotrichum sp., has been described. Reaction of 4-butyl-3,5-dimethoxyhomophthalic anhydride with hexanoyl chloride in the presence of 1,1,... |
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Synthesis of 5-chloro-8-hydroxy-6-methoxy-3-pentylisocoumarin.
J. Asian Nat. Prod. Res. 13(6) , 505-11, (2011) The synthesis of title isocoumarin, the 5-chloro analog of naturally occurring 7-chloro-8-hydroxy-6-methoxy-3-pentylisocoumarin, isolated from Tessmannia densiflora is described. Chlorination of ethyl 2-(2-ethoxy-2-oxoethyl)-4,6-dimethoxybenzoate (2) afforded... |