Hexanoyl chloride TOP1 supplier

Hexanoyl chloride TOP1 supplier Structure
Hexanoyl chloride TOP1 supplier structure
Common Name Hexanoyl chloride TOP1 supplier
CAS Number 142-61-0 Molecular Weight 134.604
Density 1.0±0.1 g/cm3 Boiling Point 152.2±3.0 °C at 760 mmHg
Molecular Formula C6H11ClO Melting Point -87°C
MSDS Chinese USA Flash Point 50.0±0.0 °C
Symbol GHS02 GHS05
GHS02, GHS05
Signal Word Danger

Remarkably regioselective deacylation of cellulose esters using tetraalkylammonium salts of the strongly basic hydroxide ion.

Carbohydr. Polym. 111 , 25-32, (2014)

Tetraalkylammonium hydroxides have been found to mediate regioselective deacylation of cellulose esters. This deacylation surprisingly shows substantial selectivity for the removal of the acyl groups at O-2/3, affording cellulose-6-O-esters by a simple, effic...

Use of multivariate statistical techniques to optimize the separation of 17 capsinoids by ultra performance liquid chromatography using different columns.

Talanta 134 , 256-63, (2015)

In this work a multivariate statistical tool (Derringer and Suich optimization) was proposed for the separation of seventeen capsinoids (natural and synthetic) using the UHPLC-DAD chromatography. Capsinoids were analyzed at 280 nm. The variables optimized wer...

One-step dispersion of cellulose nanofibers by mechanochemical esterification in an organic solvent.

ChemSusChem 5(12) , 2319-22, (2012)

Got a crush: Native cellulose can be dispersed as nanofibers in organic solvents by ball milling with esterification agents. Milling with hexanoyl chloride/DMF gives hexanoyl-coated nanofibers dispersible in several organic solvents. Milling with succinic anh...

An efficient total synthesis of ruprechstyril from Ruprechtia tangarana.

Nat. Prod. Res. 27(13) , 1153-8, (2013)

A short total synthesis of natural isocarbostyril ruprechstyril (3-n-pentyl-6-methoxy-8-hydroxy-1(2H)-isoquinolinone) isolated from Ruprechtia tangarana is reported. 6,8-Dimethoxy-3-pentylisocoumarin obtained by condensation of 3,5-dimethoxyhomophthalic anhyd...

A facile asymmetric synthesis of (s)-14-methyl-1-octadecene, the sex pheromone of the peach leafminer moth.

Molecules 18(5) , 5201-8, (2013)

An asymmetric synthesis of 14-methyl-1-octadecene, the sex pheromone of the peach leafminer moth has been achieved. The target molecule was synthesized in six linear steps and in 30.3% overall yield from commercially available hexanoyl chloride, (S)-4-benzylo...

Total synthesis and antibacterial screening of ( ± )-7-butyl-6,8-dihydroxy-3-pentyl-3,4-dihydroisochromen-1-one.

J. Asian Nat. Prod. Res. 15(10) , 1112-22, (2013)

A new total synthesis of ( ± )-7-butyl-6,8-dihydroxy-3-pentyl-3,4-dihydroisochromen-1-one, isolated as R-enantiomer from Geotrichum sp., has been described. Reaction of 4-butyl-3,5-dimethoxyhomophthalic anhydride with hexanoyl chloride in the presence of 1,1,...

Synthesis of 5-chloro-8-hydroxy-6-methoxy-3-pentylisocoumarin.

J. Asian Nat. Prod. Res. 13(6) , 505-11, (2011)

The synthesis of title isocoumarin, the 5-chloro analog of naturally occurring 7-chloro-8-hydroxy-6-methoxy-3-pentylisocoumarin, isolated from Tessmannia densiflora is described. Chlorination of ethyl 2-(2-ethoxy-2-oxoethyl)-4,6-dimethoxybenzoate (2) afforded...