(1E)-1-Propen-1-ylboronic acid
(1E)-1-Propen-1-ylboronic acid structure
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Common Name | (1E)-1-Propen-1-ylboronic acid | ||
|---|---|---|---|---|
| CAS Number | 7547-97-9 | Molecular Weight | 85.897 | |
| Density | 1.0±0.1 g/cm3 | Boiling Point | 175.6±23.0 °C at 760 mmHg | |
| Molecular Formula | C3H7BO2 | Melting Point | 123-127ºC(lit.) | |
| MSDS | Chinese USA | Flash Point | 60.0±22.6 °C | |
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Discovery of potent, selective, and orally bioavailable alkynylphenoxyacetic acid CRTH2 (DP2) receptor antagonists for the treatment of allergic inflammatory diseases.
J. Med. Chem. 20th ed., 54 , 7299-7317, (2011) New phenoxyacetic acid antagonists of CRTH2 are described. Following the discovery of a hit compound by a focused screening, high protein binding was identified as its main weakness. Optimization aimed at reducing serum protein binding led to the identificati... |
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Selective palladium-catalyzed C-F activation/carbon-carbon bond formation of polyfluoroaryl oxazolines.
J. Org. Chem. 4th ed., 77 , 1798-1804, (2012) A selective palladium-catalyzed Suzuki-Miyaura coupling reaction of polyfluorophenyl oxazolines through ortho C-F activation is described. It was found that reactions with DPPF as the ligand occurred much faster than those with other ligands. A variety of ary... |
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Highly selective nickel-catalyzed three-component coupling of alkynes with enones and alkenyl boronic acids: a novel route to substituted 1,3-dienes.
Org. Lett. 12 , 3610-3613, (2010) A highly regio- and stereoselective nickel-catalyzed three-component coupling of alkynes with enones and alkenyl boronic acids to afford highly substituted 1,3-dienes is described. The reaction can also be extended to cyclization of enynes with coupling to al... |
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The preparation of substituted pyrazoles from β,β-dibromo-enones by a tandem condensation/Suzuki-Miyaura cross-coupling process Beltran-Rodil, S.; et al.
Synlett 4 , 602-606, (2010)
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A new strategy for the synthesis of substituted dihydropyrones and tetrahydropyrones via palladium-catalyzed coupling of thioesters Fuwa, H.; et al.
Tetrahedron 67 , 4995-5010, (2011)
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Total synthesis of rodgersinol: a survey of the Cu(II)-mediated coupling of ortho-substituted phenols Jung, J.-W.; et al.
Tetrahedron 66 , 6826-6831, (2010)
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Tetrahydrobenzothiophene derivatives: conformationally restricted inhibitors of type II dehydroquinase.
ChemMedChem 2nd ed., 6 , 266-272, (2011)
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Palladium-catalyzed cross-coupling of electron-poor terminal alkynes with arylboronic acids under ligand-free and aerobic conditions.
J. Org. Chem. 76th ed., 75 , 5635-5642, (2010) Palladium-catalyzed cross-coupling reaction of terminal alkynes with arylboronic acids has been described. In the presence of Pd(OAc)(2) and Ag(2)O, a variety of terminal alkynes, including electron-poor terminal alkynes, smoothly underwent the reaction with ... |
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Highly substituted benzannulated cyclooctanol derivatives by samarium diiodide-induced cyclizations.
Beilstein J. Org. Chem. 6 , 1229-1245, (2010) A series of γ-oxo esters suitably substituted with various styrene subunits was subjected to samarium diiodide-induced 8-endo-trig cyclizations. Efficacy, regioselectivity and stereoselectivity of these reactions via samarium ketyls strongly depend on the sub... |