(2-Bromovinyl)benzene

(2-Bromovinyl)benzene Structure
(2-Bromovinyl)benzene structure
Common Name (2-Bromovinyl)benzene
CAS Number 103-64-0 Molecular Weight 183.045
Density 1.4±0.1 g/cm3 Boiling Point 220.9±9.0 °C at 760 mmHg
Molecular Formula C8H7Br Melting Point 7 °C(lit.)
MSDS Chinese USA Flash Point 101.7±0.0 °C
Symbol GHS07
GHS07
Signal Word Warning

Pathway for the stereocontrolled Z and E production of alpha,alpha-difluorine-substituted phenyl butenoates.

J. Org. Chem. 71(22) , 8618-21, (2006)

An efficient preparation of pure ethyl Z- and E-alpha,alpha-difluoro-4-phenyl-3-butenoate 1a and 1b together with the corresponding acids 2a and 2b is described. The procedures involve stereocontrolled additions of *CF2CO2Et to phenylacetylene or beta-bromost...

Identification of the brominated flame retardant 1,2-dibromo-4-(1,2-dibromoethyl)cyclohexane as an androgen agonist.

J. Med. Chem. 49 , 7366-72, (2006)

To investigate androgen receptor (AR) activation by exogenous compounds, we used a combination of experimental analysis and theoretical modeling to compare a set of brominated flame retardants (BFRs) to dihydrotestosterone (DHT) with regard to ligand docking,...

Practical one-pot conversion of aryl bromides and ß-bromostyrenes into aromatic nitriles and cinnamonitriles. Ishii G, et al.

Tetrahedron 69(5) , 1462-69, (2013)

Enantioselective Preparation of C2-Symmetrical Ferrocenyl Ligands for Asymmetric Catalysis. Schwink L and Knochel P.

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Catalytic Hunsdiecker Reaction and One-Pot Catalytic Hunsdiecker-Heck Strategy: Synthesis of α, β-Unsaturated Aromatic Halides, α-(Dihalomethyl) benzenemethanols, 5-Aryl-2, 4-pentadienoic acids, Dienoates and Dienamides. Naskar D and Roy S.

Tetrahedron 56(10) , 1369-1377, (2000)

New method for the synthesis of β-bromostyrenes. Shastin AV, et al.

Russ. Chem. Bull. 50(8) , 1401-1405, (2001)

Cross-Coupling of Tertiary Alkyl Grignard Reagents with β-Bromostyrene Catalyzed by Dichloro[1,1'-bis(diphenylphosphino)ferrocene]nickel (II). Hayashi T, et al.

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The reaction of ß-bromostyrene with nickel carbonyl in the presence of alkynes. Ryang M, et al.

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