The Journal of organic chemistry

Synthesis of o-(Dimethylamino) aryl Ketones, Acridones, Acridinium Salts, and 1 H-Indazoles by the Reaction of Hydrazones and Arynes

AV Dubrovskiy, RC Larock

Index: Gabbutt, Christopher D.; Heron, B. Mark; McCreary, Janice M.; Thomas, David A. Journal of Chemical Research - Part S, 2002 , # 2 p. 69 - 71

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Citation Number: 21

Abstract

... Reaction conditions: 0.25 mmol of benzaldehyde dimethylhydrazone, 1.1 equiv of aryne precursor and 3.0 equiv of CsF in 5 mL of MeCN were heated in a closed vial at 65 °C for 10 h. Then, 3 mL of 1 M HCl was added, and the mixture was heated at 65 °C for 2 ... Table b ... Table d ...