STUDIEN ZUM VORGANG DER WASSERSTOFFÜBERTRAGUNG 611: Chemische Reaktivität und Halbstufenpotential Vergleichende Versuche am Beispiel einiger …

L Horner, RE Schmitt

Index: Horner, Leopold; Schmitt, Rolf-Erhard Phosphorus and Sulfur and the Related Elements, 1982 , vol. 13, p. 189 - 212

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Citation Number: 6

Abstract

Abstract In arylsulfonyl halides, the half-wave potentials of the corresponding chlorides and fluorides differ by more than 1000 mV, the fluoride being more negative; the influence of para-substituents is small for the chlorides, large for the fluorides. In agreement with the half- wave potentials, arylsulfonyl chlorides are considerably more reactive chemically than the corresponding fluorides. The O-selectivity found for P (O) F compounds is not observed in ...