4-nitrobenzylbromide

Modify Date: 2024-01-02 02:12:59

4-nitrobenzylbromide Structure
4-nitrobenzylbromide structure
Common Name 4-nitrobenzylbromide
CAS Number 100-11-8 Molecular Weight 216.032
Density 1.7±0.1 g/cm3 Boiling Point 304.2±17.0 °C at 760 mmHg
Molecular Formula C7H6BrNO2 Melting Point 98 °C
MSDS Chinese USA Flash Point 137.8±20.9 °C
Symbol GHS05
GHS05
Signal Word Danger

 Names

Name 4-nitrobenzyl bromide
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.7±0.1 g/cm3
Boiling Point 304.2±17.0 °C at 760 mmHg
Melting Point 98 °C
Molecular Formula C7H6BrNO2
Molecular Weight 216.032
Flash Point 137.8±20.9 °C
Exact Mass 214.958176
PSA 45.82000
LogP 2.65
Vapour Pressure 0.0±0.6 mmHg at 25°C
Index of Refraction 1.612
Stability Stable. Incomaptible with bases, amines, oxidizing agents, alcohols. May be moisture sensitive. Corrodes steel.

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
XS7967000
CHEMICAL NAME :
Toluene, alpha-bromo-p-nitro-
CAS REGISTRY NUMBER :
100-11-8
LAST UPDATED :
199710
DATA ITEMS CITED :
6
MOLECULAR FORMULA :
C7-H6-Br-N-O2
MOLECULAR WEIGHT :
216.05
WISWESSER LINE NOTATION :
WNR D1E

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
56 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
Unscheduled DNA synthesis
TEST SYSTEM :
Rodent - rat Liver
DOSE/DURATION :
10 umol/L
REFERENCE :
ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 3,11,1981

 Safety Information

Symbol GHS05
GHS05
Signal Word Danger
Hazard Statements H314
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard Codes C:Corrosive
Risk Phrases R34
Safety Phrases S26-S36/37/39-S45
RIDADR UN 3261 8/PG 2
WGK Germany 3
RTECS XS7967000
Packaging Group II
Hazard Class 8
HS Code 29049085

 Synthetic Route

 Customs

HS Code 2904909090
Summary HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

 Articles3

More Articles
A case of multiple sensitization to three halogeno-substituted mono-nitrobenzenes.

Ital. Gen. Rev. Dermatol. 15(2) , 107-12, (1978)

A case of occupational contact dermatitis in a female chemical pharmaceutical laboratory researcher is described. The allergological investigation revealed a state of sensitization to three mono-nitro...

Synthesis of p, p'-divinylazobenzene.

Di Yi Jun Yi Da Xue Xue Bao 23(3) , 273-6, (2003)

To synthesize p, p'-divinylazobenzene (DVAB).Wittig reagent was initially synthesized using P-nitrobenzyl bromide and triphenylphosphine, followed by reaction with formaldehyde to produce p-nitro styr...

Allergic contact dermatitis from para-nitrobenzyl bromide.

Contact Dermatitis 38(4) , 232, (1998)

 Synonyms

α-Bromoparanitrotoluene
1-(Bromomethyl)-4-nitrobenzene
Benzene, 1- (bromomethyl)-4-nitro-
Toluene, α-bromo-4-nitro-
α-Bromo-4-nitrotoluene
α-Bromo-p-nitrotoluene
4-nitrobenzylbromide
MFCD00007373
EINECS 202-820-6
Benzene, 1-(bromomethyl)-4-nitro-
Toluene, α-bromo-p-nitro-
4-Nitrobenzyl bromide
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