Methyl 2-bromo-5-methoxybenzoate

Modify Date: 2024-01-10 09:55:11

Methyl 2-bromo-5-methoxybenzoate Structure
Methyl 2-bromo-5-methoxybenzoate structure
Common Name Methyl 2-bromo-5-methoxybenzoate
CAS Number 35450-36-3 Molecular Weight 245.070
Density 1.5±0.1 g/cm3 Boiling Point 291.9±20.0 °C at 760 mmHg
Molecular Formula C9H9BrO3 Melting Point N/A
MSDS Chinese USA Flash Point 130.4±21.8 °C
Symbol GHS06
GHS06
Signal Word Danger

 Names

Name methyl 2-bromo-5-methoxybenzoate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.5±0.1 g/cm3
Boiling Point 291.9±20.0 °C at 760 mmHg
Molecular Formula C9H9BrO3
Molecular Weight 245.070
Flash Point 130.4±21.8 °C
Exact Mass 243.973495
PSA 35.53000
LogP 2.69
Vapour Pressure 0.0±0.6 mmHg at 25°C
Index of Refraction 1.538

 Safety Information

Symbol GHS06
GHS06
Signal Word Danger
Hazard Statements H301-H319
Precautionary Statements P301 + P310-P305 + P351 + P338
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S45
RIDADR UN 2810 6.1/PG 3
WGK Germany 3
HS Code 2916399090

 Synthetic Route

~10%

Methyl 2-bromo-5-methoxybenzoate Structure

Methyl 2-bromo-...

CAS#:35450-36-3

Literature: Ozaki, Shigeko; Adachi, Masashi; Sekiya, Sayaka; Kamikawa, Rie Journal of Organic Chemistry, 2003 , vol. 68, # 11 p. 4586 - 4589

~91%

Methyl 2-bromo-5-methoxybenzoate Structure

Methyl 2-bromo-...

CAS#:35450-36-3

Literature: Rose, Nathan R.; Ng, Stanley S.; Mecinovic, Jasmin; Lienard, Benoit M. R.; Bello, Simon H.; Sun, Zhe; McDonough, Michael A.; Oppermann, Udo; Schofield, Christopher J. Journal of Medicinal Chemistry, 2008 , vol. 51, # 22 p. 7053 - 7056

~%

Methyl 2-bromo-5-methoxybenzoate Structure

Methyl 2-bromo-...

CAS#:35450-36-3

Literature: Yakugaku Zasshi, , vol. 76, p. 1122,1125 Chem.Abstr., , p. 3505

~86%

Methyl 2-bromo-5-methoxybenzoate Structure

Methyl 2-bromo-...

CAS#:35450-36-3

Literature: Zhu, Yan; Yan, Hong; Lu, Linhua; Liu, Defu; Rong, Guangwei; Mao, Jincheng Journal of Organic Chemistry, 2013 , vol. 78, # 19 p. 9898 - 9905

~71%

Methyl 2-bromo-5-methoxybenzoate Structure

Methyl 2-bromo-...

CAS#:35450-36-3

Literature: Barhate, Nivrutti B.; Gajare, Anil S.; Wakharkar, Radhika D.; Bedekar, Ashutosh V. Tetrahedron, 1999 , vol. 55, # 36 p. 11127 - 11142

~73%

Methyl 2-bromo-5-methoxybenzoate Structure

Methyl 2-bromo-...

CAS#:35450-36-3

Literature: Shen, Zhongqi; Siva Ramamoorthy; Hatzenbuhler, Nicole T.; Evrard, Deborah A.; Childers, Wayne; Harrison, Boyd L.; Chlenov, Michael; Hornby, Geoffrey; Smith, Deborah L.; Sullivan, Kelly M.; Schechter, Lee E.; Andree, Terrance H. Bioorganic and Medicinal Chemistry Letters, 2010 , vol. 20, # 1 p. 222 - 227

 Customs

HS Code 2918990090
Summary 2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

 Synonyms

2-Bromo-5-methoxybenzoic Acid Methyl Ester
Methyl 2-bromo-5-methoxybenzoate
MFCD00051594
2-Bromo-5-methoxy benzoic acid methyl ester
2-bromo-5-methoxy methylbenzoate
Benzoic acid, 2-bromo-5-methoxy-, methyl ester
6-Bromo-m-anisic Acid Methyl Ester
Methyl 6-Bromo-m-anisate
methyl-2-bromo-5-methoxybenzoate