2-trimethylsilyloxyfuran
2-trimethylsilyloxyfuran structure
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Common Name | 2-trimethylsilyloxyfuran | ||
|---|---|---|---|---|
| CAS Number | 61550-02-5 | Molecular Weight | 156.255 | |
| Density | 0.9±0.1 g/cm3 | Boiling Point | 148.6±0.0 °C at 760 mmHg | |
| Molecular Formula | C7H12O2Si | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 24.4±0.0 °C | |
| Symbol |
GHS02, GHS07 |
Signal Word | Danger | |
| Name | (2-Furanyloxy)Trimethylsilane |
|---|---|
| Synonym | More Synonyms |
| Density | 0.9±0.1 g/cm3 |
|---|---|
| Boiling Point | 148.6±0.0 °C at 760 mmHg |
| Molecular Formula | C7H12O2Si |
| Molecular Weight | 156.255 |
| Flash Point | 24.4±0.0 °C |
| Exact Mass | 156.060654 |
| PSA | 22.37000 |
| LogP | -1.16 |
| Vapour Pressure | 5.3±0.2 mmHg at 25°C |
| Index of Refraction | 1.437 |
| Storage condition | −20°C |
| Symbol |
GHS02, GHS07 |
|---|---|
| Signal Word | Danger |
| Hazard Statements | H225-H315-H319-H335 |
| Precautionary Statements | P210-P261-P305 + P351 + P338 |
| Personal Protective Equipment | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| Hazard Codes | F: Flammable;Xi: Irritant; |
| Risk Phrases | R11 |
| Safety Phrases | S26 |
| RIDADR | UN 1993 3/PG 2 |
| WGK Germany | 3 |
| Packaging Group | III |
| Hazard Class | 3.2 |
| HS Code | 2932190090 |
|
~80%
2-trimethylsily... CAS#:61550-02-5 |
| Literature: Pelter; Ward; Sirit Tetrahedron Asymmetry, 1994 , vol. 5, # 9 p. 1745 - 1762 |
|
~84%
2-trimethylsily... CAS#:61550-02-5 |
| Literature: Evans, David A.; Kvaerno, Lisbet; Dunn, Travis B.; Beauchemin, Andre; Raymer, Brian; Mulder, Jason A.; Olhava, Edward J.; Juhl, Martin; Kagechika, Katsuji; Favor, David A. Journal of the American Chemical Society, 2008 , vol. 130, # 48 p. 16295 - 16309 |
|
~87%
2-trimethylsily... CAS#:61550-02-5 |
| Literature: Niknam, Khodabakhsh; Zolfigol, Mohammad Ali; Saberi, Dariush; Molaee, Hajar Journal of the Chinese Chemical Society, 2009 , vol. 56, # 6 p. 1257 - 1264 |
|
~57%
2-trimethylsily... CAS#:61550-02-5 |
| Literature: Camici, Lucia; Dembech, Pasquale; Ricci, Alfredo; Seconi, Giancarlo; Taddei, Maurizio Tetrahedron, 1988 , vol. 44, # 13 p. 4197 - 4206 |
|
~78%
2-trimethylsily... CAS#:61550-02-5 |
| Literature: Fiorenza, Mariella; Ricci, Alfredo; Romanelli, M. Novella; Taddei, Maurizio; Dembech, Pasquale; Seconi, Giancarlo Heterocycles, 1982 , vol. 19, # 12 p. 2327 - 2329 |
| Precursor 8 | |
|---|---|
| DownStream 9 | |
CAS#:367-64-6
CAS#:124083-30-3
CAS#:18688-70-5
CAS#:3249-33-0
CAS#:2407-43-4
CAS#:21053-98-5
CAS#:2833-30-9![tert-butyl (4S)-4-[(S)-hydroxy-[(2S)-5-oxo-2H-furan-2-yl]methyl]-2,2-dimethyl-1,3-oxazolidine-3-carboxylate structure](https://image.chemsrc.com/caspic/378/131613-93-9.png)
CAS#:131613-93-9| HS Code | 2932190090 |
|---|---|
| Summary | 2932190090 other compounds containing an unfused furan ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0% |
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Simple diastereoselectivity of the BF3.OEt2-catalyzed vinylogous Mukaiyama aldol reaction of 2-(trimethylsiloxy)furans with aldehydes.
J. Org. Chem. 70(9) , 3654-9, (2005) [reaction: see text] A comprehensive scan of the transition state space for the reaction of 2-(trimethylsiloxy)furan and methacrolein (24 combinations) offered a satisfactory explanation of the high l... |
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Nucleophilic addition reaction of 2-trimethylsilyloxyfuran to N-gulosyl-C-alkoxymethylnitrones: synthetic approach to polyoxin C.
Org. Lett. 4 , 1111, (2002) [reaction: see text] The stereoselectivity of nucleophilic addition of 2-trimethylsilyloxyfuran to N-gulosyl-C-alkoxymethylnitrones was investigated. It was found that the selectivity was highly depen... |
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G. Desimoni et al.
Tetrahedron 57 , 10203, (2001)
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| 2-(Trimethylsilyloxy)furan |
| furan-2-yloxy(trimethyl)silane |
| 2-trimethylsilyloxyfuran |
| Silane, (2-furanyloxy)trimethyl- |
| (2-Furyloxy)(trimethyl)silane |
| MFCD00011729 |