(S)-(+)-Epichlorhydrin

Modify Date: 2024-01-02 20:40:21

(S)-(+)-Epichlorhydrin Structure
(S)-(+)-Epichlorhydrin structure
 Common Name (S)-(+)-Epichlorhydrin
CAS Number 67843-74-7 Molecular Weight 92.524
Density 1.2±0.1 g/cm3 Boiling Point 116.1±0.0 °C at 760 mmHg
Molecular Formula C3H5ClO Melting Point −57 °C(lit.)
MSDS Chinese USA Flash Point 33.9±0.0 °C
Symbol GHS02 GHS05 GHS06 GHS08
GHS02, GHS05, GHS06, GHS08		 Signal Word Danger

 Names

Name (S)-epichlorohydrin
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.2±0.1 g/cm3
Boiling Point 116.1±0.0 °C at 760 mmHg
Melting Point −57 °C(lit.)
Molecular Formula C3H5ClO
Molecular Weight 92.524
Flash Point 33.9±0.0 °C
Exact Mass 92.002892
PSA 12.53000
LogP 0.45
Vapour density 3.2 (vs air)
Vapour Pressure 22.0±0.2 mmHg at 25°C
Index of Refraction 1.444
Water Solubility insoluble

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
RR0427100
CHEMICAL NAME :
Oxirane, (chloromethyl)-, (S)-
CAS REGISTRY NUMBER :
67843-74-7
BEILSTEIN REFERENCE NO. :
1420784
LAST UPDATED :
199612
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C3-H5-Cl-O
MOLECULAR WEIGHT :
92.53

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Mutation test systems - not otherwise specified

MUTATION DATA

TEST SYSTEM :
Rodent - mouse
DOSE/DURATION :
100 mg/kg
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 298,197,1993

 Safety Information

Symbol GHS02 GHS05 GHS06 GHS08
GHS02, GHS05, GHS06, GHS08
Signal Word Danger
Hazard Statements H226-H301 + H311 + H331-H314-H317-H350
Precautionary Statements P201-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P308 + P313
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes T:Toxic
Risk Phrases R10;R23/24/25;R34;R43;R45
Safety Phrases S53-S45
RIDADR UN 2023 6.1/PG 2
WGK Germany 3
RTECS TX4900000
Packaging Group II
Hazard Class 6.1
HS Code 2910900090

 Synthetic Route

 Customs

HS Code 2910900090
Summary 2910900090. epoxides, epoxyalcohols, epoxyphenols and epoxyethers, with a three-membered ring, and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

 Articles39

More Articles
Kinetics of dextran crosslinking by epichlorohydrin: a rheometry and equilibrium swelling study.

Carbohydr. Polym. 92(2) , 1792-8, (2013)

Curing behavior and gel properties of dextran are investigated during its crosslinking by epichlorohydrin (ECH) using rheometry and equilibrium swelling studies. Each ECH/anhydroglucose unit of differ...

Adsorptive decolorization of methylene blue by crosslinked porous starch.

Carbohydr. Polym. 93(2) , 374-9, (2013)

Crosslinked porous starch (CPS) was prepared by two steps. Native starch was crosslinked with epichlorohydrin and then CPS was prepared by hydrolyzing the crosslinked starch with α-amylase. As a biode...

Genotoxic effects of ethylene oxide, propylene oxide and epichlorohydrin in humans: update review (1990-2001).

Mutat. Res. 512(2-3) , 173-94, (2002)

Ethylene oxide (EtO), propylene oxide (PO) and epichlorohydrin (ECH) are important industrial chemicals widely used as intermediates for various synthetic products. EtO and PO are also environmental p...

 Synonyms

MFCD00005132
EINECS 203-439-8
Oxirane, 2-(chloromethyl)-, (2S)-
T3OTJ B1G &&(S)-(+)- Form
(S)-3-Chloropropylene Oxide
(S)-(+)-Epichlorohydrin
(2S)-2-(Chloromethyl)oxirane
5-17-01-00021 (Beilstein Handbook Reference)
(S)-(+)-2-(CHLOROMETHYL) OXIRANE
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